Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
To commence the ebullition of To commence the dissociation of
water under ordinary pressure, aqueous vapor under ordinary
a temperature of 100° C., or pressures, a temperature of
212° F., must be attained. 2800° C., or 5072° F., must be
attained.
To complete the ebullition of a To complete the dissociation of
given quantity of water, an a given quantity of aqueous
amount of heat must be applied, vapor, an amount of heat must
sufficient to have raised be applied sufficient to have
the water 537° C., or 968° F., raised the vapor 4532° C., or
above its boiling-point, had it 8158° F., above its dissociation-
not evaporated. point had it not decomposed.
In order that a given quantity of In order that a given quantity of
vapor of water shall condense, the elements of water may combine,
it must give off sufficient heat they must give off sufficient
to raise its own weight of water heat to raise their own
537° C., or 968° F. weight of aqueous vapor 4532°
C., or 8158° F.
I have expressed these generalizations and analogies rather more
definitely than they have been hitherto stated, but those who are
acquainted with the researches of Deville, Cailletet, Bunsen, etc.,
will perceive that I am justified in doing so.[2]
With the general laws of the dissociation of water thus before us,
we may follow out the necessary action of the above-stated pressure
and consequent evolution of heat in the lower regions of the solar
atmosphere upon the large proportion of aqueous vapor which I have
shown that it should contain.
It is evident that the first result will be separation of this water
into its elements, accompanied with a loss of temperature corresponding
to the latent heat of dissociation. We may assume that in the lower
regions of the solar atmosphere the free heat evolved by mechanical
compression will be more than sufficient to dissociate the whole of the
aqueous vapor, and thus the dissociated gases will be left at a higher
temperature than was necessary to effect their dissociation. Their
condition will thus be analogous to that of superheated steam: they
will have to give off some heat before they can _begin_ to combine.[3]
There will, however, be somewhere an elevation at which the heat
evolved by the joint compression of the elementary and combined gases
will be just sufficient to dissociate the latter, and here will be the
meeting surface of the combined and the uncombined constituents of
water. There will be a sphere containing combined oxygen and hydrogen
surrounded by an atmospheric envelope containing large quantities of
aqueous vapor, and the temperature at this limiting surface will be
equal to that of the oxyhydrogen flame under a corresponding pressure.
Public-domain text, read in full here on John Shaqi.
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