Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
What will occur under these conditions? Will the “detonating gases”
behave as in the laboratory? Obviously not, as a glance at the third
of the above parallel propositions will show. The dissociated gases
cannot combine without giving off their 4532° of latent heat as actual
temperature. This can only be effected by communication with matter
which is cooler than itself.
If a bubble of steam is surrounded by water maintained at the boiling
temperature, it will not condense at all, because any effort of
condensation would be accompanied with an evolution of heat exactly
sufficient to evaporate its own result. If, however, the surrounding
water is slowly radiating, or otherwise losing its heat, the enclosed
bubble of steam will condense proportionately, by giving off to its
envelope an amount of its latent heat just sufficient to maintain the
water at the boiling-point.
For further illustration, let us conceive the case of a certain
quantity of the elements of water heated exactly to the temperature
of dissociation, and confined in a vessel the sides of which are
maintained externally at precisely the same temperature as the
gases within, so that no heat can be added or taken away from them.
No sensible amount of combination can take place, as the first
infinitesimal effort of combustion, or combination, would set free
just the amount of heat required to decompose its own result. Let us
now suppose a modification of these conditions, viz., that the vessel
containing the dissociated gases, at the temperature of dissociation,
shall be surrounded with bodies cooler than itself, _i.e._, capable
of receiving more heat from it than they radiate towards it; there
would then take place just so much combustion as would set free the
amount of heat required to maintain the temperature of the vessel at
the dissociation-point; or, in other words, combustion would go on to
the extent of setting free just so much heat as the gaseous mass was
capable of radiating, or otherwise transmitting to surrounding bodies;
and this amount of combustion would continue till all the gases had
combined.
We have only to give this hypothetical vessel a spherical form and an
internal diameter of 853,380 miles—to construct its enveloping sides
of a thick shell of aqueous vapor, etc., and then, by placing in the
midst of the contained dissociated gases a nucleus of some kind, we
are hypothetically supplied with, the main conditions which I suppose
to exist in the sun.
Public-domain text, read in full here on John Shaqi.
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