If brine is allowed to evaporate slowly, the molecules of the salt
arrange themselves, as the water leaves them, in beautifully regular
cubical crystals. You may see them form easily enough if you watch a
drop of brine gradually dry up under a microscope. The salt crystals
contain nothing but salt. If they are heated till they become red-hot
they pass into the fluid state; and when still further heated, the fluid
salt becomes a vapour or gas and, as such, flies off into the air, or
=volatilizes=.
Thus we see that when salt and water are brought into contact, the salt
undergoes a certain amount of change, while the water does not remain
wholly unchanged. For brine no longer boils at 212°, but requires a
considerably higher temperature. The salt, as it were, holds the water
back, and prevents it from assuming the gaseous state under the same
conditions as if it were pure, just as, in the previous case, the water
held the alcohol back; or we may say that the force of heat which drives
the molecules of liquid water apart, when steam is formed, has a greater
resistance to overcome when salt is dissolved in the water. And just as
the presence of alcohol lowers the freezing point of the water with
which it is mixed, so does the presence of salt lower the freezing point
of water. Sea water, which is a weak brine, begins to freeze at about
27°; and the ice which is formed is quite pure, while the remainder of
the sea water becomes richer in salt.
If we mean by attraction that which opposes any force which tends to
separate bodies, then we may say that the molecules of salt and those of
water attract one another. And such attraction between molecules of
matter of different kinds is called =chemical attraction=.
54. =Quicklime and Water: Plaster of Paris and Water: Combination.=
Quicklime is a substance obtained by heating chalk or limestone to
redness. When pure, it is a white hard solid which can be made to pass
into the liquid and gaseous states only at enormously high temperatures.
If a lump of fresh quicklime be placed in a saucer and about one-third
of its weight of water poured upon it, there will be a great turmoil,
heat will be evolved, the water will disappear, and the lime will
crumble down into a soft white powder. This operation is what
bricklayers call =slaking= lime. And if no more water has been added
than the proportion mentioned, the pure white powder which results will
be solid and dry, the water having, to all appearance, vanished.
Public-domain text, read in full here on John Shaqi.
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