In the solution of salt we saw a solid become fluid under the influence
of water; in the slaking of lime the fluid water enters into the
structure of a solid. If more water is added, this solid dissolves or
becomes liquid, as the salt did, and the solution is called =limewater=.
By carefully managed evaporation of the water the lime may be recovered
in the form of crystals, just as the salt was recovered. But there is
this difference, that the salt crystals contain no water, while the lime
crystals not only contain water, but contain exactly the same proportion
as exists in slaked lime, that is to say, 18 parts water to 56 parts
lime.
The water thus bound up with the lime into a new solid holds on so
firmly to the lime that it requires a red heat to separate the two. The
lime and the water are said to be =chemically combined=; and as the
proportion of lime and water in slaked lime, or lime crystals, is always
the same, they are said to be combined in =definite proportions=; and
the slaked lime receives the special name of =hydrate of lime=.
=Gypsum= or =Plaster of Paris= is a dry white powder. If mixed with a
little water it does not slake after the fashion of quick lime, but the
mixture soon =sets= or becomes hard; and, at the same time, the greater
part of the water disappears. In fact, it has combined with the plaster
of Paris and forms part of another hydrate, in which, when the
superfluous moisture dries, not a trace of water is to be seen. It is
this property which is taken advantage of when plaster of Paris is used
in making casts and moulds. The fluid plaster is poured over and round
the body to be cast; as a fluid, it applies itself conveniently to all
the inequalities of its surface; and, when it sets, it retains the shape
which it has thus acquired. Set plaster of Paris may be perfectly dry;
but it nevertheless contains between ⅐ and ⅛ of its weight of water,
fixed and forming an integral part of the solid hydrate. And if the set
plaster is strongly heated, the combined water is driven off and it
returns to its original state.
Gypsum is found abundantly in nature, in the shape of beautiful
transparent crystals which are called =selenite=. These crystals have
the same composition as set plaster, that is to say, they are hydrates.
A thin flake of such a crystal viewed with the highest powers of the
microscope appears perfectly homogeneous. Nevertheless, there is good
reason for the conclusion that it consists of molecules of water and
molecules of gypsum which hold together so strongly that they form a
hard brittle glassy solid. Moreover, the molecules of the hydrate itself
hold together more strongly in some directions than in others. It is
very easy to split the crystals lengthwise; while much more force is
needed to cut them crosswise and then they do not split, but break.
Public-domain text, read in full here on John Shaqi.
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