Scientific American Supplement, No. 1082, September 26, 1896Various
Science
Scientific American Supplement, No. 1082, September 26, 1896
Various
Science -- Periodicals
In the second series of experiments I employed liquid air, boiling
under a pressure of 10 mm. of mercury. The helium was first confined
under a pressure of 140 atmospheres, and then allowed to expand till
the pressure fell to twenty atmospheres, or, in some cases, to one
atmosphere. The results of these experiments were also negative, the
gas remained perfectly clear during the expansion, and not the
slightest trace of liquid could be detected. The boiling point of
liquid air was taken, from my previous determination, to be -220° C.
(Comptes Rendus, 1885, p. 238). This number cannot, however, be taken
as a constant, as the liquid air, boiling under reduced pressure,
becomes gradually poorer in nitrogen. Further, the quantity of
nitrogen lost by the liquid air on partial evaporation varies not only
with the rate of boiling, but even according to the manner in which it
has been liquefied.
If air, under high pressure, be cooled first to the temperature of
boiling ethylene, and then to -150° C., it liquefies, and, on reducing
the pressure slowly, liquid air is obtained boiling under atmospheric
pressure. During the process a considerable quantity of the liquid air
evaporates, and the proportion of nitrogen to oxygen in the remaining
liquid is less than in air liquefied under high pressure. If the
liquid air obtained by this process be made to boil under a pressure
of 10 mm. of mercury, the proportion of nitrogen in the mixture
continues to decrease, but, on account of the large quantity of oxygen
present, the liquid does not solidify, although its temperature is
some six degrees below the freezing point of nitrogen. When, as in
some of my former experiments, the air was liquefied under normal
pressure by means of liquid oxygen boiling under a pressure of 10 mm.
of mercury, the ratio of nitrogen to the oxygen in the liquid air was
the same as in the gaseous air from which it had been produced. The
liquid air, obtained by direct condensation at normal pressure,
appeared to lose oxygen and nitrogen with about equal rapidity, and at
the end of the experiment a considerable quantity of liquid nitrogen
remained behind in the apparatus. On reducing the pressure to 10 mm.
of mercury the nitrogen solidified. Prof. Dewar has stated that liquid
air solidifies as such, the solid product containing a slightly
smaller percentage of nitrogen than is present in the atmosphere. My
experiments have proved this statement to be incorrect; liquid oxygen
does not solidify even when boiling under a pressure of 2 mm. of
mercury.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account