Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
Taking the latent heat of steam as 537° C., and multiplying this number
by 14.74, the evaporative power of the coal used in these experiments,
its equivalent in calories is 7,915. From the analysis of this coal,
disregarding the nitrogen and deducting an equivalent of hydrogen
for the oxygen present, the _total heat units_ given by Favre and
Silbermann's figures for carbon (8,080) and hydrogen (34,462) will
be 8,746. It will be seen, therefore, that the calorific power, as
determined by Thompson's apparatus, gives a much lower result when
multiplied by 537 than the heat units calculated from the chemical
composition of the coal. When I used Thompson's apparatus in the
chemical laboratory at Turin to determine the evaporative power of
various cargoes of South Wales coal, it was agreed by mutual consent
that the temperature of the water at starting should be 39° F. (the
temperature at which the _heat unit_ was determined). The temperature
of the room was about 60°, but this varied, as the weather was somewhat
severe and changeable. Under these conditions, with the water at 39° and
room 60°, the coal which gives 14.74 lb. of water per lb. of coal,
will give as high as 15.88 lb. of water per lb. of coal. This result
multiplied by 537=8,496 calories, approaching much more nearly to the
theoretic value. This method of working is still practiced abroad, but
experience has shown that very widely differing results follow when
working in this manner, especially if the temperature of the room is
changeable, as it naturally is where ash determinations and other
chemical work is proceeding simultaneously. The time the experiment
lasts, taking the reading on a quickly rising thermometer and other
considerations, render the experiments anything but trustworthy when
0.2 of a degree makes a difference of more than 100 calories. In the
instructions supplied with Thompson's calorimeter nothing is said as to
the temperature of the room in which the experiment is performed, but
simply that the water shall be at 60° F. If, with the water at 60°, a
room were at 50°, as it often is in winter, a good coal would give 14
lb. of water per lb. of coal as the evaporative power; but if in summer,
the room were at 75° and the water at 60°, the same coal would give 15
lb. of water per lb. of coal. If further evidence were needed of the
effect of temperature consideration of the experiments already referred
to will show how necessary it is that some general rule shall be
adopted. Considerable stress is laid (in the instructions) upon the
quantity of oxygen mixture used being determined by rough experiments.
This I have found leads to erroneous conclusions unless a number of
experiments are tried in the calorimeter, as it often happens that the
quantity which appears to be best adapted is not that which yields a
trustworthy result. There are many samples of South Wales coal, 30
grains of which will require 10 parts of oxygen mixture in order to burn
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