Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
completely, but since a little oxygen is lost in drying and grinding,
and few samples of chlorate are free from chloride, it is not safe to
use less than 11 parts of oxygen mixture, but this amount is sufficient
in _all_ cases, and never need be exceeded. I have made numerous
experiments with various coals (anthracite, steam, semi-bituminous, and
bituminous, including a specimen of the ten yard coal of Derbyshire),
and find that with 11 parts of chlorate and nitrate of potash, they are
all perfectly manageable and yield the best results. It is quite clear
that the excess of chlorate is decomposed in all instances, and the
latent heat of the oxygen evolved, but those coals which are best to
experiment with did not yield results that differed when the quantity of
oxygen mixture was reduced to nearly the limit required for combustion
of the coal. Under these circumstances, therefore, the constant use
of 11 parts of oxygen mixture--a suitable quantity for all coals
exported--would enable operators to obtain similar figures, and make the
test uniform in different hands.
The following is a brief outline of the method of procedure recommended:
Sample the coal until an average portion passes through a sieve having
64 meshes to the square inch. Take about 300 grains (20 grammes) of this
and run through a brass wire gauze having 4,600 meshes to the square
inch, taking care that the whole sample selected is thus treated. One
part of nitrate of potash and 3 parts of chlorate of potash (dry) are
separately ground in a mortar, and repeatedly sifted through another
wire gauze sieve, having 1,000 meshes to the square inch, in order that
the oxygen mixture shall _not_ be ground to an impalpable powder, as
this is very undesirable. It absorbs moisture rapidly, and interferes
with the regularity of the combustion when very fine. 330 grains of the
powder are weighed out (after drying), and intimately incorporated
with 30 grains of coal--better with a spatula than by rubbing in a
mortar--and then introduced into a copper cylinder (3½ inches long by ¾
inch wide, made from a copper tube), and pressed down in small portions
by a test-tube with such firmness as is required by the nature of the
coal, not tapped on the bottom, since the rougher portions of the oxygen
mixture rise to the surface. As the temperature of a room is almost
invariably much higher than the water supply, a little hot water is
added to that placed in the glass cylinder, until the difference of
temperature between the water and the room is about the mark indicated
in the following table:
Room at The water should be
80° F. 70° F.
72 64
67 60
60 54
55 50
50 46
42 40
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