Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
Mr. Müntz's method of procedure is as follows: He submits to
distillation three or four gallons of snow, rain, or sea water in an
apparatus such as shown in Fig. 1. The part which serves as a boiler,
and which holds the liquid to be distilled, is a milk-can, B. The vapors
given off through the action of the heat circulate through a leaden tube
some thirty-three feet in length, and then traverse a tube inclosed
within a refrigerating cylinder, T, which is kept constantly cold by a
current of water. They are finally condensed in a glass flask, R, which
forms the receiver. When 100 or 150 cubic centimeters of condensed
liquid (which contains all the alcohol) are collected in the receiver,
the operations are suspended. The liquid thus obtained is distilled anew
in a second apparatus, which is analogous to the preceding but much
smaller (Fig. 2). The liquid is heated in the flask, B, and its vapor,
after traversing a glass worm, is condensed in the tube, T. The
operation is suspended as soon as five or six cubic centimeters of the
condensed liquid have been collected in the test-tube, R. The latter is
now removed, and to its liquid contents, there is added a small quantity
of iodine and carbonate of soda. The mixture is slightly heated, and
soon there are seen forming, through precipitation, small crystals of
iodoform. Under such circumstances, iodoform could only have been formed
through the presence of an alcohol in the liquid. These analytical
operations are verified by Mr. Müntz as follows: He distills in the same
apparatus three to four gallons of chemically pure distilled water, and
ascertains positively that under these conditions iodine and carbonate
of soda give absolutely no reaction. Finally, to complete the
demonstration and to ascertain the approximate quantity of alcohol
contained in natural waters, he undertakes the double fractional
distillation of a certain quantity of pure water to which he has
previously added a one-millionth part of alcohol. Under these
circumstances the iodine and carbonate of soda give a precipitate of
iodoform exactly similar to that obtained by treating natural waters.
[Illustration: Fig. 3.--IODOFORM CRYSTALS OBTAINED DIRECTLY (greatly
magnified).]
[Illustration: FIG. 4,--IODOFORM CRYSTALS OBTAINED WITH RAIN WATER.]
In the case of arable soil, Mr. Müntz stirs up a weighed quantity of the
material to be analyzed in a certain proportion of water, distills it in
the smaller of the two apparatus, and detects the alcohol by means of
the same operation as before.
[Illustration: FIG. 5.--IODOFORM CRYSTALS OBTAINED WITH SNOW WATER.]
Public-domain text, read in full here on John Shaqi.
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