Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
The formation of iodoform by precipitation under the action of iodine
and carbonate of soda is a very sensitive test for alcohol. Iodoform
has sharply defined characters which allow of its being very easily
distinguished. Its crystalline form, especially, is entirely typical,
its color is pale yellowish, and, when it is examined under the
microscope, it is seen to be in the form of six-pointed stars precisely
like the crystalline form of snow. Mr. Müntz has not been contented to
merely submit the iodoform precipitates obtained by him to microscopical
examination, but has preserved the aspect of his preparations by
means of micro-photography. The figures annexed show some of the most
characteristic of the proofs. Fig. 1 shows crystals of iodoform obtained
with pure water to which one-millionth part of alcohol had been added.
Fig. 2 exhibits the form of the crystals obtained with rain water; and
Fig. 3, those with water. Fig. 4 shows crystals obtained with arable
soil or garden mould. The first of Mr. Müntz's experiments were made
about four years ago; but since that time he has treated a great number
of rain and snow waters collected both at Paris and in the country. At
every distillation all the apparatus was cleansed by prolonged washing
in a current of steam; and, in order to confirm each analysis, a
corresponding experiment was made like the one before mentioned. More
than eighty trials gave results which were exactly identical. The
quantity of alcohol contained in rain, snow, and sea waters may be
estimated at from one to several millionths. Cold water and melted snow
seem to contain larger proportions of it than tepid waters. In the
waters of the Seine it is found in appreciable quantities, and in sewage
waters the proportions increase very perceptibly. Vegetable mould is
quite rich in it; indeed it is quite likely that alcohol in its natural
state has its origin in the soil through the fermentation of the organic
matters contained therein. It is afterward disseminated throughout the
atmosphere in the state of vapor and becomes combined with the aqueous
vapors whenever they become condensed. The results which we have just
recorded are, as far as known to us, absolutely new; they constitute a
work which is entirely original, which very happily goes to complete the
history of the composition of the soil and atmosphere, and which does
great credit to its author.--_La Nature_.
[Illustration: FIG. 6.--IODOFORM CRYSTALS OBTAINED WITH VEGETABLE
MOULD.]
* * * * *
DETECTION OF ALCOHOL IN TRANSPARENT SOAPS.
By H. JAY.
Public-domain text, read in full here on John Shaqi.
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