Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
results will be worked out if the coke exceeds the above amount although
I have met with coals giving 87 per cent. of coke which were perfectly
manageable, though in other cases the coal did not burn completely. It
will be noted that the non-volatile residue of anthracite is never as
low as 86 per cent., and this, together with the very dry steam coals
and bastard anthracite (found over a not inextensive tract of the South
Wales Coal field), form a series of coals, alike difficult to burn in
Thompson's calorimeter. Considerable experience has shown that in no
single instance was the true comparative heating power of anthracite
or bastard anthracite indicated. With a view to accelerate the perfect
combustion of these coals, sugar, starch, bitumen, and bituminous
coals--substances rich in hydrogen--were employed, mixed in varying
proportions with the anthracitic coal, but without the anticipated
effect. Coke was also treated in a like manner. Without enlarging
further upon these futile trials--all carefully and repeatedly
verified--the results of my experiments and experience show that for
coals of an anthracitic character, yielding more than 87 per cent. of
coke, or for coke itself, Thompson's calorimeter is not suited as an
indicator of their comparative calorific power, for the simple reason
that some of the carbon is so graphitic in its nature that it will not
burn perfectly when mixed with nitrate and chlorate of potash. A sample
of very pure anthracite used in the experiments referred to, gave 90.4
per cent. of non-volatile residue, and only 0.84 per cent. of ash. This
coal was not difficult to experiment with, as combustion started with
comparative ease and proceeded quite rapidly enough, but in every
instance a portion of the carbon was unconsumed, and consequently
instead of about 13° of rise in temperature only 10° were recorded.
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