Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
Since the calorific power of a coal is determined by the number of
degrees Fahrenheit which a given quantity of water is raised in
temperature by a known weight of fuel, it follows that every care should
be taken that the experiment be performed under similar atmospheric
conditions. The oscillation of barometric pressure does not appear to
affect the working, but the temperature of the room in which the
work was done, and especially that of the water, are most important
considerations. It has been observed by some who have used this
apparatus--and I have frequently noticed it myself--that the lower the
temperature of the water is under which the fuel is burnt the higher is
the result found. This has been explained on the assumption that the
colder the water used, the greater is the difference between the
temperature of the room and that of the water; hence it would be
expedient that in all cases when such experiments are made the same
difference of temperature between the air in the room and the water
employed should always exist. For example, if the temperature of the
room were 70°, and the water at 60°, then the same coal would give a
like result with the water at 40° and the room at 50°. This has been
regarded as the more evident, because the gases passing through
the water escape under favorable conditions of working at the same
temperature as the water, and are perfectly deprived of any heat in
excess of that possessed by the water. Under these circumstances it
would seem only reasonable that this assumption should be correct. It
was, however, found after a large number of experiments upon the same
sample of coal that this was not the case. 30 grammes of coal which
raises the temperature of the water 13.4°, when the water at starting
was 60° and the room at 70°, gives 13.7° rise of temperature with the
water at 40° and the room at 50°. Conversely, when the water is at 70°
and the room at 80°, a lower result is obtained. The explanation appears
to be this: The gas which escapes from the water was not in existence in
the gaseous form previous to the experiment, and the heat communicated
to the gas being a definite quantity it follows that the more the gas
is cooled the greater the proportion of chemical energy in the shape of
heat will be utilized and recorded as calorific power.
In order, therefore, to make the experiment more simple and workable
at all temperatures, a sample of coal was selected, which should be
perfectly manageable and readily consumed. Appended is an analysis of
the coal employed (from Ebbw Vale, Monmouthshire):
Composition per cent.
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