Scientific American Supplement, No. 470, January 3, 1885Various
Science
Scientific American Supplement, No. 470, January 3, 1885
Various
Science -- Periodicals
Generally, a liquid has considerably greater density than its vapor. But,
if a vessel containing both is heated, the liquid experiences a dilatation
which is gradually augmented till it equals and even exceeds that of the
gas; whence, of course, an equal volume of the liquid will weigh less and
less. On the other hand, a constantly larger quantity of vapor is formed,
which accumulates above the liquid and becomes heavier and heavier. Now if
the density of the vapor increases, and that of the liquid diminishes,
they will reach a point, under a suitable temperature, when they will be
the same. There will then be no reason for the liquid to sink or the vapor
to rise, or for the existence of any line of separation between them, and
they will be mixed and confounded. They will no longer be distinguishable
by their heat of constitution. It is true that, in passing into the state
of a vapor, a liquid absorbs a great deal of latent heat, but that is
employed in scattering the molecules and keeping them at a distance; and
there will be none of it if the distance does not increase. We are then,
at this stage of our experiments, in the presence of a critical point, at
which we do not know whether the matter is liquid or gaseous; for, in
either condition, it has the same density, the same heat of constitution,
and the same properties. It is a new state, the gaso-liquid state. An
experiment of Cagniard-Latour re-enforced this explanation of the
phenomena. Heating ether in closed vessels to high temperatures, he
brought it to a point where the liquid could be made wholly to disappear,
or to be suddenly reformed on the slightest elevation or the slightest
depression of temperature accordingly as it was raised just above or
cooled to just below the critical point. The discovery of these properties
suggested an explanation of the failure of previous attempts to liquefy
air. Air at ordinary low temperatures is in the gaso-liquid condition, and
its liquefaction is not possible except when a difference exists between
the density of the vapor and that of the liquid greater than it is
possible to produce under any conditions that can exist then. It was
necessary to reduce the temperature to below the critical point; and it
was by adopting this course that MM. Cailletet and Raoul Pictet achieved
their success. The rapid escape of the compressed gas itself from a
condition of great condensation at an extremely low temperature was
employed as the agent for producing a greater degree of cold than it had
been possible before to obtain. M. Cailletet used oxygen escaping at -29°
C. from a pressure of three hundred atmospheres; M. Raoul Pictet, the same
gas escaping at -140° from a pressure of three hundred and twenty
atmospheres; and both obtained oxygen and nitrogen, and M. Pictet
hydrogen, in what they thought was a liquid, and possibly even in a solid
form.
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