Scientific American Supplement, No. 470, January 3, 1885 — John Shaqi
Scientific American Supplement, No. 470, January 3, 1885Various
Science
Scientific American Supplement, No. 470, January 3, 1885
Various
Science -- Periodicals
Still, it could not be asserted that hydrogen and the elements of the air
had been completely liquefied. These gases had not yet been seen collected
in the static condition at the bottom of a tube and separated from their
vapors by the clearly defined concave surface which is called a
_meniscus._ The experiments had, however, proved that liquefaction is
possible at a temperature of below -120° C. (-184° Fahr.). To make the
process practicable, it was only necessary to find sufficiently powerful
refrigerants; and these were looked for among gases that had proved more
refractory than carbonic acid and protoxide of nitrogen. M. Cailletet
selected ethylene, a hydrocarbon of the same composition as illuminating
gas, which, when liquefied by the aid of carbonic acid and a pressure of
thirty-six atmospheres, boils at -103° C. (-153° Fahr.). M. Wroblewski, of
Cracow, who had witnessed some of M. Cailletet's experiments, and obtained
his apparatus, and M. Olzewski, in association with him, also experimented
with ethylene, and had the pleasure of recording their first complete
success early in April, 1883. Causing liquid ethylene to boil in an
air-pump vacuum at -103° C., they were able to produce a temperature of
-150° C. (-238° Fahr.), the lowest that had ever been observed. Oxygen,
having been previously compressed in a glass tube, became a permanent
liquid, with a clearly defined meniscus. It presented itself, like the
other liquefied gases, under the form of a transparent and colorless
substance, resembling water, but a little less dense. Its critical point
was marked at -113° C. (-171° Fahr.), below which the liquid could be
formed, but never above it; while it boiled rapidly at -186° C. (-303°
Fahr.). A few days afterward, the Polish professors obtained the
liquefaction of nitrogen, a more refractory gas, under a pressure of
thirty-six atmospheres, at -146° C. (-231° Fahr.). Long, difficult, and
expensive operations were required to produce this result, for the extreme
degree of cold it demanded had to be produced by boiling large quantities
of ethylene in a vacuum. M. Cailletet devised a cheaper process, by
employing another hydrocarbon that rises from the mud of marshes, and is
called _formene_. It is less easily liquefied than ethylene, but for that
very reason can be boiled in the air at a lower temperature, or at -160°C.
(-256° Fahr.); and at this temperature nitrogen and oxygen can be
liquefied in a bath of formene as readily as sulphurous acid in the common
freezing mixture.
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