Scientific American Supplement, No. 470, January 3, 1885Various
Science
Scientific American Supplement, No. 470, January 3, 1885
Various
Science -- Periodicals
MM. Cailletet, Wroblewski, and Olzewski have continued their experiments
in liquefaction, and acquired increased facility in the handling of liquid
ethylene, formene, atmospheric air, oxygen, and nitrogen. M. Olzewski was
able to report to the French Academy of Sciences, on the 21st of July,
1884, that by placing liquefied nitrogen in a vacuum he had succeeded in
producing a temperature of -213°C. (-351° Fahr.), under which hydrogen was
liquefied. Contrary to the suppositions founded on the metallic behavior
of this element, that it would present the appearance of a molten metal,
like mercury, the liquid had the mobile behavior and the transparency of
the hydrocarbons.
* * * * *
EXAMINATION OF FATS.
The methods employed up to the present in examination of fats, animal and
vegetable, are mere reactions lacking general application; scattered
throughout the literature, and doubtful with regard to reliability, they
are of little or no value to the experimenter--an approximate quantitative
examination even of a simple mixture being exceedingly difficult if not
impossible, since the qualitative composition of fatty substances is the
same, and the separation of the nearer components impracticable. The
object of analysis consisted in estimating the accompanying impurities of
fat, as, resin, albuminoids, and pigments. The nature of these substances
depends on the mode of extraction and preservation of the fat, and are
subject in the course of time to alteration. The only reaction based upon
the chemical constitution of fat is produced by treatment of oleic or
linoleic acid with nitrous acid, which therefore is of some value in the
examination of drying oils. Of general application are the methods which
correspond to the chemical constitution of fats, and thus determine the
relative quantity of the components; advantage can then be derived from
qualitative reactions, inasmuch as they further affirm the result of the
quantitative test, or dispel any doubt with regard to the correctness of
the result. The principal methods which comply with these demands have
been carefully studied by Hueble for the purpose of discovering a process
of general application; methods founded on the determination of density,
freezing, and melting point were compared with those dependent on the
solubility of fatty substances in glacial acetic acid or a mixture of
alcohol and acetic acid; also the method of Hehner for testing of butter,
the determination of glycerine and oleic acid, and at length the process
of saponification. Nearly all fats contain members belonging to one of the
three series of fatty acids, _e.g._, acids of the type of acetic acid
(stearic and palmitic acids); such as are derivatives of acrylic acid
(oleic and erucic acids); and such as are homologues of tetrolic acid
(linoleic acid). It is likely that the relative quantity of each of these
acids is variable, with regard to the same fat, within definite limits,
Public-domain text, read in full here on John Shaqi.
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