Scientific American Supplement, No. 483, April 4, 1885Various
Science
Scientific American Supplement, No. 483, April 4, 1885
Various
Science -- Periodicals
Although the manufacture of soluble glass does not strictly belong to the
glass maker's art, yet it is an allied process to that of manufacturing
glass. Of late soluble glass has been used with good effect as a
preservative coating for stones, a fire-proofing solution for wood and
textile fabrics. Very thin gauze dipped in a solution of silicate of
potash diluted with water, and dried, burns without flame, blackens, and
carbonizes as if it were heated in a retort without contact of air. As a
fire-proofing material it would be excellent were it not that the
alkaline reaction of this glass very often changes the coloring matters
of paintings and textile fabrics. Since soluble glass always remains
somewhat deliquescent, even though the fabrics may have been thoroughly
dried, the moisture of the atmosphere is attracted, and the goods remain
damp. This is the reason why its use has been abandoned for preserving
theater decorations and wearing apparel. Another application of soluble
glass has been made by surgeons for forming a protecting coat of silicate
around broken limbs as a substitute for plaster, starch, or dextrine.
The only use where soluble glass has met with success is in the
preservation of porous stones, building materials, paintings in
distemper, and painting on glass. Before we describe these applications,
we will give the processes used in making soluble glass.
The following ingredients are heated in a reverberatory furnace until
fusion becomes quieted: 1,260 pounds white sand, 660 pounds potash of
78°. This will produce 1,690 pounds of transparent, homogeneous glass,
with a slight tinge of amber. This glass is but little soluble in hot
water. To dissolve it, the broken fragments are introduced into a iron
digester charged with a sufficient quantity of water, at a high pressure,
to make a solution marking 33° to 35° Baume. Distilled or rain water
should be used, as the calcareous salts contained in ordinary water would
produce insoluble salts of lime, which would render the solution turbid
and opalescent; this solution contains silica and potash combined
together in the proportion of 70 to 30.
Silicate of soda is made with 180 parts of sand, 100 parts carbonate of
soda (0.91), and is to be melted in the same manner as indicated
previously.
Soluble glass may also be prepared by the following method: A mixture of
sand with a solution of caustic potash or soda is introduced into an iron
boiler, under 5 or 6 atmospheres of pressure, and heated for a few hours.
The iron boiler contains an agitator, which is occasionally operated
during the melting. The liquid is allowed to cool until it reaches 212°,
and is drawn out after it has been allowed to clear by settling; it is
then concentrated until it reaches a density of 1.25, or it may be
evaporated to dryness in an iron kettle. The metal is not affected by
alkaline liquors.
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