Scientific American Supplement, No. 483, April 4, 1885Various
Science
Scientific American Supplement, No. 483, April 4, 1885
Various
Science -- Periodicals
The glass is soluble in boiling water; cold water dissolves but little of
it. The solution is decomposed by all acids, even by carbonic acid.
Soluble glass is apparently coagulated by the addition of an alkaline
salt; mixed with powdered matters upon which alkalies have no effect, it
becomes sticky and agglutinative, a sort of mineral glue.
To apply soluble glass for the preservation of buildings and monuments of
porous materials, take a solution of silicate of potash of 35° Baume,
dilute it with twice its weight of water, paint with a brush, or inject
with a pump; give several coats. Experience has shown that three coats
applied on three successive days are sufficient to preserve the materials
indefinitely, at a cost of about 15 cents per square yard. When applied
upon old materials, it is necessary to wash them thoroughly with water.
The degree of concentration of the solutions to be used varies with the
materials. For hard stones, such as sand and free stones, rock, etc., the
solution should mark 7° to 9° Baume; for soft stones with coarse grit, 5°
to 7°; for calcareous stones of soft texture, 6° to 7°. The last coating
should always be applied with a more dilute solution of 3° to 4° only.
Authorities are divided upon the successful results of the preservation
of stone by silicates. Some claim in the affirmative that the protection
is permanent, while others assert that with time and the humidity of the
atmosphere the beneficial effects gradually disappear. It might be worth
while to experiment upon some of the porous sandstones, which, under the
extreme influence of our climate, rapidly deteriorate; such, for
instance, as the Connecticut sandstone, so popular at one time as a
building material, but which is now generally discarded, owing to its
tendency to crumble to pieces when exposed to the weather even for a few
years.
Soluble glass has also been used in Germany to a great extent for mural
painting, known as stereochromy. The process consists in first laying a
ground with a lime water; when this is thoroughly dry, it is soaked with
a solution of silicate of soda. When this has completely solidified, the
upper coating is applied to the thickness of about one-sixteenth of an
inch, and should be put on very evenly. It is then rubbed with fine
sandstone to roughen the surface. When thoroughly dry, the colors are
applied with water; the wall is also frequently sprinkled with water. The
colors are now set by using a mixture of silicate of potash completely
saturated with silica, with a basic silicate of soda (a flint liquor with
soda base, obtained by melting 2 parts sand with 3 parts of carbonate of
soda). As the colors applied do not stand the action of the brush, the
soluble glass is projected against the wall by means of a spray. After a
few days the walls should be washed with alcohol to remove the dust and
alkali liberated.
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