Scientific American Supplement, No. 611, September 17, 1887Various
Science
Scientific American Supplement, No. 611, September 17, 1887
Various
Science -- Periodicals
The gases from a large limekiln supply the dilute carbonic acid gas,
which contains 25 per cent. to 30 per cent. of pure gas, the principal
diluting gas being, of course, nitrogen. This kiln gas is drawn from
the kiln by a blowing engine, and is first cooled in two large
receivers. It is then forced into the solution of sodium carbonate in
the absorption tower, 65 ft. high by 6 ft. diameter, filled with the
liquor. The tower has many diaphragms and perforated "mushrooms," to
cause a proper dispersion of the gases as they ascend through the
liquor. The strength of liquor found best adapted for the work is
equal to a density of about 30 deg. Twaddell. After saturation the mud of
bicarbonate of sodium is drawn off and passed into the "decomposer," a
tower 35 ft. high by 6 ft. 6 in. in diameter, with perforated shelves,
into which steam is blown from below, the liquor passing downward. The
bicarbonate is decomposed, pure carbonic acid being given off. This is
passed through a scrubber and into a gas holder ready for use. The
liquor, which has now returned to the state of simple carbonate of
sodium, only requires cooling to be ready to absorb a fresh lot of
carbonic acid gas. The cooling is effected in a tower packed loosely
with bricks, the hot liquor trickling down against a powerful current
of air blown in from below. Liquor has been cooled in this way, in
once passing through the tower, from 220 deg. Fahr. to 58 deg. Fahr., but of
course the exact cooling obtained depends more or less on the
temperature of the atmosphere.
The next stage of the process, if we follow on after the preparation
of the pure carbonic acid, is the employment of the gas for the
decomposition of the ammonium sulphide absorbed in a brine liquor as
above explained. The brine and ammonium sulphide are contained in what
is known as a "Solvay tower," provided with proper means for
dispersion and absorption of the carbonic acid gas. The precipitated
bicarbonate of sodium is removed and washed, and prepared for the
market in whatever form is required, the sulphureted hydrogen gas
being led to a holder and stored, as before stated.
The decomposition of the ammonium chloride by means of "alkali waste"
is carried out in a specially designed still. This is a tower 45 ft.
high by 8 ft. diameter, divided by horizontal plates into compartments
of about 3 ft. 8 in. in height. These compartments communicate with
one another by means of pockets, or recesses, in the shell of the
tower. A vertical shaft, with arms, revolves in the tower. The "waste"
is fed in at the top by means of hopper and screw feed. The liquor is
heated by steam blown in to over 212 deg. Fahr. The ammonium sulphide is
led direct into an absorbing vessel full of brine.
Public-domain text, read in full here on John Shaqi.
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