Scientific American Supplement, No. 611, September 17, 1887 — John Shaqi
Scientific American Supplement, No. 611, September 17, 1887Various
Science
Scientific American Supplement, No. 611, September 17, 1887
Various
Science -- Periodicals
In outline the process is as follows: We will suppose that a quantity
of bicarbonate of sodium has been just precipitated from a brine
solution, and we have the residual ammonium chloride to deal with.
This is decomposed by "alkali waste," giving a final liquor of calcium
chloride, which is run to waste, and a quantity of ammonium sulphide
gas. This latter is led at once into a solution of salt in water, till
saturation takes place. Into this liquor of brine and ammonium
sulphide _pure_ carbonic acid gas is now passed. The ammonium sulphide
is decomposed, pure sulphureted hydrogen gas is given off, which is
conducted to a gas holder and stored, while ammonium bicarbonate is
formed in the liquor, which brings about the conversion of the salt
into bicarbonate of sodium, ready for removal and preparation for the
market.
It will be observed that we printed the word _pure_ in italics in
speaking of the carbonic acid used. This is one of the great points in
the process, as in order that the sulphureted hydrogen gas obtained
shall be concentrated and pure, only pure carbonic acid can be used in
liberating it. The apparatus employed in its preparation is perhaps
the most ingenious part of the works, and well worthy of attention by
others besides alkali makers. The method is based on the fact that if
dilute impure carbonic acid is passed into a solution of carbonate of
sodium, the carbonic acid is absorbed, bicarbonate of sodium being
formed, and the diluting gases passing away.
The bicarbonate of sodium on heating gives up the extra carbonic acid,
which can be collected and stored pure, while the liquor passes back
to simple carbonate of sodium, to be used over again as an absorbent.
This is not at all new in theory, of course, nor is this the first
proposal to use it commercially; but it is claimed that this is the
first successful working of it on a large scale.
Public-domain text, read in full here on John Shaqi.
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