Scientific American Supplement No. 819, September 12, 1891Various
Science
Scientific American Supplement No. 819, September 12, 1891
Various
Science -- Periodicals
In order to obtain a resistance of 0.0001 of an ohm,
it is necessary to sensibly satisfy the equation
20,000 l/s = 1/10,000
_l_ expressing the thickness of the voltameter expressed in meters,
and _s_ being the section in square millimeters. For example: For l =
1/10, s = 20,000,000, say 20 square meters. It will be seen from this
example what should be the proportions of apparatus designed for a
production on a large scale.
The new principles that permit of the construction of such voltameters
are as follows: (1) the substitution of an alkaline for the acid
solution, thus affording a possibility of employing iron electrodes;
(2) the introduction of a porous partition between the electrodes, for
the purpose of separating the gases.
_Electrolytic Liquid._--Commandant Renard's experiments were made with
15 per cent, solution of caustic soda and water containing 27 per
cent. of acid. These are the proportions that give the maximum of
conductivity. Experiments made with a voltameter having platinum
electrodes separated by an interval of 3 or 4 centimeters showed that
for a determinate E.M.F. the alkaline solution allows of the passage
of a slighter intenser current than the acidulated water, that is to
say, it is less resistant and more advantageous from the standpoint of
the consumption of energy.
_Porous Partition._--Let us suppose that the two parts of the trough
are separated by a partition containing small channels at right angles
with its direction. It is these channels alone that must conduct the
electricity. Their conductivity (inverse of resistance) is
proportional to their total section, and inversely proportional to
their common length, whatever be their individual section. It is,
therefore, advantageous to employ partitions that contain as many
openings as possible.
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