Scientific American Supplement No. 819, September 12, 1891Various
Science
Scientific American Supplement No. 819, September 12, 1891
Various
Science -- Periodicals
The separating effect of these partitions for the gas is wholly due to
capillary phenomena. We know, in fact, that water tends to expel gas
from a narrow tube with a pressure inversely proportional to the
tube's radius. In order to traverse the tube, the gaseous mass will
have to exert a counter-pressure greater than this capillary pressure.
As long as the pressure of one part and another of the wet wall
differs to a degree less than the capillary pressure of the largest
channel, the gases disengaged in the two parts of the trough will
remain entirely separate. In order that the mixing may not take place
through the partition above the level of the liquid (dry partition),
the latter will have to be impenetrable in every part that emerges.
The study of the partitions should be directed to their separating
effect on the gases, and to their electric resistance. In order to
study the first of these properties, the porous partition, fixed by a
hermetical joint to a glass tube, is immersed in the water (Fig. 2).
An increasing pressure is exerted from the interior until the passage
of bubbles is observed. The pressure read at this moment on the
manometer indicates (transformed above the electrolytic solution) the
changes of level that the bath may undergo. The different porcelains
and earths behave, from this point of view, in a very unequal manner.
For example, an earthen vessel from the Pillivayt establishment
supports some decimeters of water, while the porcelain of Boulanger,
at Choisy-le-Roi, allows of the passage of the gas only at pressures
greater than one atmosphere, which is much more than is necessary.
Wire gauze, canvas, and asbestos cloth resist a few centimeters of
water. It might be feared, however, that the gases, violently
projected against these partitions, would not pass, owing to the
velocity acquired. Upon this point experiment is very reassuring.
After filling with water a canvas bag fixed to the extremity of a
rubber tube, it is possible to produce in the interior a tumultuous
disengagement of gas without any bubbles passing through.
[Illustration: FIG. 2.--ARRANGEMENT FOR THE STUDY OF CAPILLARY
REACTION IN POROUS VESSELS.]
From an electrical point of view, partitions are of very unequal
quality. Various partitions having been placed between electrodes
spaced three centimeters apart, currents were obtained which indicated
that, with the best of porcelains, the rendering of the apparatus is
diminished by one-half. Asbestos cloth introduces but an insignificant
resistance.
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