Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
You think he has found at last the source of the acid and alkali in the
impurities of the water. So thought Davy, but he was too faithful a
disciple of Bacon to leave this legitimate inference unverified.
Accordingly, he repeatedly distilled the water from a silver alembic
until it left absolutely no residue on evaporation, and then with water
which he knew to be pure, and contained in vessels of gold from which he
knew it could acquire no taint, he still again repeated the already
well-tried experiment. He dipped his test-paper into the vessel
connected with the positive pole, and the water was still decidedly
acid. He dipped the paper into the vessel connected with the negative
pole, and the water was still alkaline.
You might well think that Davy would have been discouraged here. But not
in the least. The path to the great truths which Nature hides often
leads through a far denser and a more bewildering forest than this; but
then there is not infrequently a "blaze" on the trees which points out
the way, although it may require a sharp eye in a clear head to see the
marks. And Davy was well enough trained to observe a circumstance which
showed that he was now on the right path and heading straight for the
goal.
On examining the alkali formed in this last experiment, he found that
it was not, as before, a fixed alkali, soda or potash, but the volatile
alkali ammonia. Evidently the fixed alkali came from the impurities of
the water, and when, on repeating the experiment with pure water in
agate cups or glass tubes, the same results followed, he felt assured
that so much at least had been established. There was still, however,
the production of the volatile alkali and of nitrous acid to be
accounted for. As these contain only the elements of air and water, Davy
thought that possibly they might be formed by the combination of
hydrogen at the one pole and of oxygen at the other with the nitrogen of
the air, which was necessarily dissolved in the water. In order,
therefore, to eliminate the effect of the air, he again repeated the
experiment under the receiver of an air-pump from which the atmosphere
had been exhausted, but still the acid and alkali appeared in the two
cups.
Public-domain text, read in full here on John Shaqi.
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