Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
In Davy's first experiments the two glass tubes which he used to contain
the water were connected together by an animal membrane, and he found,
on immersing the poles of his battery in their respective tubes, that,
besides the now well-known gases, there were really formed muriatic acid
in one tube, and a fixed alkali in the other. Davy at once, however,
suspected that the acid and alkali came from common salt contained in
the animal membrane, and he therefore rejected this material and
connected the glass tubes by carefully washed cotton fiber, when, on
submitting the water as before to the action of the voltaic current, and
continuing the experiment through a great length of time, no _muriatic_
acid appeared; but he still found that the water in the one tube was
strongly alkaline, and in the other strongly acid, although the acid was
chiefly, at least, nitrous acid. A part of the acid evidently came from
the animal membrane, but not the whole, and the source of the alkali was
as obscure as before.
Davy then made another guess. He knew that alkali was used in the
manufacture of glass; and it occurred to him that the glass of the
tubes, decomposed by the electric current, might be the origin of the
alkali in his experiments. He therefore substituted for the glass tubes
cups of agate, which contains no alkali, and repeated the experiment,
but still the troublesome acid and alkali appeared. Nevertheless, he
said, it is possible that these products may be derived from some
impurities existing in the agate cups, or adhering to them; and so, in
order to make his experiments as refined as possible, he rejected the
agate vessels and procured two conical cups of pure gold, but, on
repeating the experiments, the acid and alkali again appeared.
And now let me ask who is there of us who would not have concluded at
this stage of the inquiry that the acid and alkali were essential
products of the decomposition of water? But not so with Davy. He knew
perfectly well that all the circumstances of his experiments had not
been tested, and until this had been done he had no right to draw such a
conclusion. He next turned to the water he was using. It was distilled
water, which he supposed to be pure, but still, he said, it is possible
that the impurities of the spring-water may be carried over to a slight
extent by the steam in the process of distillation, and may therefore
exist in my distilled water to a sufficient amount to have caused the
difficulty. Accordingly, he evaporated a quart of this water in a silver
dish, and obtained seven-tenths of a grain of dry residue. He then added
this residue to the small amount of water in the gold cones and again
repeated the experiment. The proportion of alkali and acid was sensibly
increased.
Public-domain text, read in full here on John Shaqi.
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