Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
_Palm Kernel Oil_, which is obtained from the kernels of the palm tree
of West Africa, is used in soap making to replace cocoanut oil where the
lower price warrants its use. It resembles cocoanut oil in respect to
saponification and in forming a very similar soap. Kernel oil is white
in color, has a pleasant nutty odor when fresh, but rapidly develops
free acid, which runs to a high percentage.
_Palm Oil_ is produced from the fruit of the several species of the palm
tree on the western coast of Africa generally, but also in the
Philippines. The fresh oil has a deep orange yellow tint not destroyed
by saponification, a sweetish taste and an odor of orris root or violet
which is also imparted to soap made from it. The methods by which the
natives obtain the oil are crude and depend upon a fermentation, or
putrefaction. Large quantities are said to be wasted because of this
fact. The oil contains impurities in the form of fermentable fibre and
albuminous matter, and consequently develops free fatty acid rapidly.
Samples tested for free acid have been found to have hydrolized
completely and one seldom obtains an oil with low acid content. Because
of this high percentage of free fatty acid, the glycerine yield is
small, though the neutral oil should produce approximately 12 per cent.
glycerine. Some writers claim that glycerine exists in the free state
in palm oil. The writer has washed large quantities of the oil and
analyzed the wash water for glycerine. The results showed that the
amount present did not merit its recovery. Most soap makers do not
attempt to recover the glycerine from this oil, when used alone for soap
manufacture.
There are several grades of palm oil in commerce, but in toilet soap
making it is advisable to utilize only Lagos palm oil, which is the best
grade. Where it is desired to maintain the color of the soap this oil
produces, a small quantity of the lower or "brass" grade of palm oil may
be used, as the soap made from the better grades of oil gradually
bleaches and loses its orange yellow color.
Palm oil produces a crumbly soap which cannot readily be milled and is
termed "short." When used with tallow and cocoanut oil, or 20 to 25 per
cent. cocoanut oil, it produces a very satisfactory toilet soap. In the
saponification of palm oil it is not advisable to combine it with tallow
in the kettle, as the two do not readily mix.
Since the finished soap has conveyed to it the orange color of the oil,
the oil is bleached before saponification. Oxidation readily destroys
the coloring matter, while heat and light assist materially. The methods
generally employed are by the use of oxygen developed by bichromates and
hydrochloric acid and the direct bleaching through the agency of the
oxygen of the air.
CHROME BLEACHING OF PALM OIL.
The chrome process of bleaching palm oil is more rapid and the oxygen
thus derived being more active will bleach oils which air alone cannot.
It depends upon the reaction:
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