Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The reasons for keeping samples in a dark, cool place are obvious. This
is to prevent any increase in rancidity and any undue increase in free
fatty acids. In the case of many fats the committee has found in its
co-operative analytical work that free acid tends to increase very
rapidly. This tendency is minimized by low temperatures.
MOISTURE AND VOLATILE MATTER.
After careful consideration the committee has decided that moisture is
best determined in a vacuum oven of the design which accompanies the
above report. Numerous results on check samples have confirmed the
committee's conclusions. The oven recommended by the committee is
constructed on the basis of well-known principles and it is hoped that
this type will be adopted generally by chemists who are called upon to
analyze fats and oils. The experiments of the committee indicate that it
is a most difficult matter to design a vacuum oven which will produce
uniform temperatures throughout; and one of the principal ideas in the
design adopted is uniformity of temperature over the entire single
shelf. This idea has not quite been realized in practice but,
nevertheless, the present design approaches much closer to the ideal
than other vacuum ovens commonly used. In the drawing the essential
dimensions are those between the heating units and the shelf and the
length and breadth of the outer casting. The standard Fat Analysis
Committee Oven (F. A. C. Oven) can be furnished by Messrs. E. H. Sargent
& Company, 125 West Lake street, Chicago.
The committee realizes that for routine work a quicker method is
desirable and has added one such method and has also stated the
conditions under which comparable results can be obtained by means of
the ordinary well-ventilated air oven held at 105 to 110deg. C. However,
in accordance with a fundamental principle adopted by the committee at
its first meeting, only one standard method is adopted and declared
official for each determination.
The committee realizes that in the case of all methods for determining
moisture by means of loss on heating there may be a loss due to volatile
matter (especially fatty acids) other than water. The title of the
determination MOISTURE AND VOLATILE MATTER indicates this idea, but any
considerable error from this source may occur only in the case of high
acid fats and oils and particularly those containing lower fatty acids
such as coconut and palm kernel oil. In the case of extracted greases
which have not been properly purified, some of the solvent may also be
included in the moisture and volatile matter determination, but inasmuch
as the solvent, usually a petroleum product, can only be considered as
foreign matter, for commercial purposes, it is entirely proper to
include it with the moisture.
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