Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
Oleic acid (red oil) and stearic acid are obtained usually by the
saponification of oils, fats and greases by acid, lime or water under
pressure or Twitchelling. The fatty acids thus are freed from their
combination with glycerine and solidify upon cooling, after which they
are separated from the water and pressed at a higher or lower
temperature. The oleic acid, being liquid at ordinary temperature,
together with some stearic and palmitic acid, is thus pressed out. These
latter acids are usually separated by distillation, combined with the
press cake further purified and sold as stearic acid.
The red oil, sometimes called saponified red oil, is often semi-solid,
resembling a soft tallow, due to the presence of stearic acid. The
distilled oils are usually clear, varying in color from light to a deep
brown. Stearic acid, which reaches the trade in slab form, varies in
quality from a soft brown, greasy, crumbly solid of unpleasant odor to a
snow white, wax-like, hard, odorless mass. The quality of stearic acid
is best judged by the melting point, since the presence of any oleic
acid lowers this. The melting point of the varieties used in soap
manufacture usually ranges from 128deg. to 132deg. F. Red oil is used in
the manufacture of textile soaps, replacing olive oil foots soap for
this purpose, chlorophyll being used to color the soap green. Stearic
acid, being the hard firm fatty acid, may be used in small quantities to
give a better grade of soap body and finish. In adding this substance it
should always be done in the crutcher, as it will not mix in the kettle.
It finds its largest use for soap, however, in the manufacture of
shaving soaps and shaving creams, since it produces the non-drying
creamy lather so greatly desired for this purpose. Both red oil and
stearic acid being fatty acids, readily unite with the alkali
carbonates, carbon dioxide being formed in the reaction and this method
is extensively used in the formation of soap from them.
RANCIDITY OF OILS AND FATS.
Rancidity in neutral oils and fats is one of the problems the soap
manufacturer has to contend with. The mere saying that an oil is rancid
is no indication of its being high in free acid. The two terms rancidity
and acidity are usually allied. Formerly, the acidity of a fat was
looked upon as the direct measure of its rancidity. This idea is still
prevalent in practice and cannot be too often stated as incorrect. Fats
and oils may be _acid_, or _rancid_, or _acid and rancid_. In an acid
fat there has been a hydrolysis of the fat and it has developed a rather
high percentage of free acid. A rancid fat is one in which have been
developed compounds of an odoriferous nature. An acid and rancid fat is
one in which both free acid and organic compounds of the well known
disagreeable odors have been produced.
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