Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
_Olive Oil_, which comes from the fruit of the olive trees, varies
greatly in quality, according to the method by which it is obtained and
according to the tree bearing the fruit. Three hundred varieties are
known in Italy alone. Since the larger portion of olive oil is used for
edible purposes, a lower grade, denatured oil, denatured because of the
tariff, is used for soap manufacture in this country. The oil varies in
color from pale green to golden yellow. The percentage of free acid in
this oil varies greatly, though the oil does not turn rancid easily. It
is used mainly in the manufacture of white castile soap.
Olive oil foots, which is the oil extracted by solvents after the better
oil is expressed, finds its use in soap making mostly in textile soaps
for washing and dyeing silks and in the production of green castile
soaps.
Other oils, as poppy seed oil, sesame oil, cottonseed oil, rape oil,
peanut (arachis) oil, are used as adulterants for olive oil, also as
substitutes in the manufacture of castile soap, since they are cheaper
than olive oil.
_Cottonseed Oil_ is largely used in the manufacture of floating and
laundry soaps. It may be used for toilet soaps where a white color is
not desired, as yellow spots appear on a finished soap in which it has
been used after having been in stock a short time.
_Corn Oil and Soya Bean Oil_ are also used to a slight extent in the
manufacture of toilet soaps, although the oils form a soap of very
little body. Their soaps also spot yellow on aging.
Corn oil finds its greatest use in the manufacture of soap for washing
automobiles. It is further employed for the manufacture of cheap liquid
soaps.
_Fatty Acids_ are also used extensively in soap manufacture. While the
soap manufacturer prefers to use a neutral oil or fat, since from these
the by-product glycerine is obtained, circumstances arise where it is
an advantage to use the free fatty acids. Red oil (oleic acid, elaine)
and stearic acid are the two fatty acids most generally bought for soap
making. In plants using the Twitchell process, which consists in
splitting the neutral fats and oils into fatty acids and glycerine by
dilute sulphuric acid and producing their final separation by the use of
so-called aromatic sulphonic acids, these fatty acids consisting of a
mixture of oleic, stearic, palmitic acids, etc., are used directly after
having been purified by distillation, the glycerine being obtained from
evaporating the wash water.
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