Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant. — John Shaqi
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The introduction of hardened oils has opened a new source of raw
material for the soap manufacturer in that it is now possible to use
oils in soap making which were formerly discarded because of their
undesirable odors. Thus fish or train oils which had up to the time of
oil hydrogenating resisted all attempts of being permanently deodorized,
can now be employed very satisfactorily for soap manufacture. A Japanese
chemist, Tsujimoto[3] has shown that fish oils contain an unsaturated
acid of the composition C_{18}H_{28}O_{2}, for which he proposed the
name clupanodonic acid. By the catalytic hardening of train oils this
acid passes to stearic acid and the problem of deodorizing these oils is
solved.[4]
At first the introduction of hardened oils for soap manufacture met with
numerous objections, due to the continual failures of obtaining a
satisfactory product by the use of same. Various attempts have now shown
that these oils, particularly hardened train oils, produce
extraordinarily useful materials for soap making. These replace
expensive tallow and other high melting oils. It is of course impossible
to employ hardened oils alone, as a soap so hard would thus be obtained
that it would be difficultly soluble in water and possess very little
lathering quality. By the addition of 20-25% of tallow oil or some other
oil forming a soft soap a very suitable soap for household use may be
obtained. Ribot[5] discusses this matter fully. Hardened oils readily
saponify, may be perfumed without any objections and do not impart any
fishy odor to an article washed with same. Meyerheim[6] states that
through the use of hydrogenated oils the hardness of soap is
extraordinarily raised, so that soap made from hardened cottonseed oil
is twelve times as hard as the soap made from ordinary cottonseed oil.
This soap is also said to no longer spot yellow upon aging, and as a
consequence of its hardness, is able to contain a considerably higher
content of rosin through which lathering power and odor may be improved.
Hardened oils can easily be used for toilet soap bases, provided they
are not added in too great a percentage.
The use of hardened oils is not yet general, but there is little doubt
that the introduction of this process goes a long way toward solving the
problem of cheaper soap material for the soap making industry.
GREASE.
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