Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
Grease varies so greatly in composition and consistency that it can
hardly be classed as a distinctive oil or fat. It is obtained from
refuse, bones, hides, etc., and while it contains the same constituents
as tallow, the olein content is considerably greater, which causes it to
be more liquid in composition. Grease differs in color from an off-white
to a dark brown. The better qualities are employed in the manufacture of
laundry and chip soap, while the poorer qualities are only fit for the
cheapest of soaps used in scrubbing floors and such purposes. There is
usually found in grease a considerable amount of gluey matter, lime and
water. The percentage of free fatty acid is generally high.
The darker grades of grease are bleached before being used. This is done
by adding a small quantity of sodium nitrate to the melted grease and
agitating, then removing the excess saltpeter by decomposing with
sulphuric acid. A better method of refining, however, is by
distillation. The chrome bleach is also applicable.
ROSIN (COLOPHONY, YELLOW ROSIN, RESINA).
Rosin is the residue which remains after the distillation of turpentine
from the various species of pines. The chief source of supply is in the
States of Georgia North and South Carolina. It is a transparent, amber
colored hard pulverizable resin. The better grades are light in color
and known as water white (w. w.) and window glass (w. g.). These are
obtained from a tree which has been tapped for the first year. As the
same trees are tapped from year to year, the product becomes deeper and
darker in color until it becomes almost black.
The constituents of rosin are chiefly (80-90%) abietic acid or its
anhydride together with pinic and sylvic acids. Its specific gravity is
1.07-1.08, melting point about 152.5 C., and it is soluble in alcohol,
ether, benzine, carbon disulfide, oils, alkalis and acetic acid. The
main use of rosin, outside of the production of varnishes, is in the
production of laundry soaps, although a slight percentage acts as a
binder and fixative for perfumes in toilet soaps and adds to their
detergent properties. Since it is mainly composed of acids, it readily
unites with alkaline carbonates, though the saponification is not quite
complete and the last portion must be completed through the use of
caustic hydrates, unless an excess of 10% carbonate over the theoretical
amount is used. A lye of 20deg. B. is best adapted to the saponification of
rosin when caustic hydrates are employed for this purpose, since weak
lyes cause frothing. While it is sometimes considered that rosin is an
adulterant for soap, this is hardly justifiable, as it adds to the
cleansing properties of soap. Soaps containing rosin are of the well
known yellowish color common to ordinary laundry soaps. The price of
rosin has so risen in the last few years that it presents a problem of
cost to the soap manufacturer considering the price at which laundry
soaps are sold.
ROSIN SAPONIFICATION.
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