Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
_Caustic soda_ is received by the consumer in iron drums weighing
approximately 700 lbs. each. The various grades are designated as 60,
70, 74, 76 and 77%. These percentages refer to the percentage of sodium
oxide (Na_{2}O) in 100 parts of pure caustic soda formed by the
combination of 77-1/2 parts of sodium oxide and 22-1/2 parts of water,
77-1/2% being chemically pure caustic soda. There are generally
impurities present in commercial caustic soda. These consist of sodium
carbonate, sodium chloride or common salt and sometimes lime. It is
manufactured by treating sodium carbonate in an iron vessel with calcium
hydroxide or slaked lime, or by electrolysis of common salt. The latter
process has yet been unable to compete with the former in price.
Formerly all the caustic soda used in soap making was imported, and it
was only through the American manufacturer using a similar container to
that used by foreign manufacturers that they were able to introduce
their product. This prejudice has now been entirely overcome and most of
the caustic soda used in this country is manufactured here.
CAUSTIC POTASH.
The output of the salts containing potassium is controlled almost
entirely by Germany. Formerly the chief source of supply of potassium
compounds was from the burned ashes of plants, but about fifty years ago
the inexhaustible salt mines of Stassfurt, Germany, were discovered.
The salt there mined contains, besides the chlorides and sulphates of
sodium, magnesium, calcium and other salts, considerable quantities of
potassium chloride, and the Stassfurt mines at present are practically
the entire source of all potassium compounds, in spite of the fact that
other localities have been sought to produce these compounds on a
commercial basis, especially by the United States government.
After separating the potassium chloride from the magnesium chloride and
other substances found in Stassfurt salts the methods of manufacture of
caustic potash are identical to those of caustic soda. In this case,
however, domestic electrolytic caustic potash may be purchased cheaper
than the imported product and it gives results equal to those obtained
by the use of the imported article, opinions to the contrary among soap
makers being many. Most of the caustic potash in the United States is
manufactured at Niagara Falls by the Niagara Alkali Co., and the Hooker
Electrochemical Co., chlorine being obtained as a by-product. The latter
concern employs the Townsend Cell, for the manufacture of electrolytic
potash, and are said to have a capacity for making 64 tons of alkali
daily.
Public-domain text, read in full here on John Shaqi.
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