Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The soaps formed from naphthenic acids have recently been
investigated[8] and found to resemble the soaps made from cocoanut oil
and palm kernel oil, in that they are difficult to salt out and
dissociate very slightly with water. The latter property makes them
valuable in textile industries when a mild soap is required as a
detergent, e. g., in the silk industry. These soaps also possess a high
solvent power for mineral oils and emulsify very readily. The mean
molecular weight of naphthenic acids themselves is very near that of the
fatty acids contained in cocoanut oil, and like those of cocoanut oil a
portion of the separated acids are volatile with steam. The iodine
number indicates a small content of unsaturated acids.
That naphthenic acids are a valuable soap material is now recognized,
but except in Russia the soap is not manufactured to any extent at the
present time.
ALKALIS.
The common alkali metals which enter into the formation of soap are
sodium and potassium. The hydroxides of these metals are usually used,
except in the so called carbonate saponification of free fatty acids in
which case sodium and potassium carbonate are used. A water solution of
the caustic alkalis is known as lye, and it is as lyes of various
strengths that they are added to oils and fats to form soap. The density
or weight of a lye is considerably greater than that of water, depending
upon the amount of alkali dissolved, and its weight is usually
determined by a hydrometer. This instrument is graduated by a
standardized scale, and while all hydrometers should read alike in a
liquid of known specific gravity, this is generally not the case, so
that it is advisable to check a new hydrometer for accurate work against
one of known accuracy. In this country the Baume scale has been adopted,
while in England a different graduation known as the Twaddle scale is
used. The strength of a lye or any solution is determined by the
distance the instrument sinks into the solution, and we speak of the
strength of a solution as so many degrees Baume or Twaddle which are
read to the point where the meniscus of the lye comes on the graduated
scale. Hydrometers are graduated differently for liquids of different
weights. In the testing of lyes one which is graduated from 0deg. to
50deg. B. is usually employed.
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