Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
1. Boiling the fats and oils in open kettles by open steam with
indefinite quantities of caustic alkali solutions until the finished
soap is obtained; ordinarily named _full boiled soaps_. These may be
sub-divided into (a) hard soaps with sodium hydrate as a base, in which
the glycerine is recovered from the spent lyes; (b) hard soaps with soda
as a base, in which the glycerine remains in the soap, e. g., marine
cocoanut oil soaps; (c) soft potash soaps, in which the glycerine is
retained by the soap.
2. Combining the required amount of lye for complete saponification of a
fat therewith, heating slightly with dry heat and then allowing the
saponification to complete itself. This is known as the _cold process_.
3. Utilizing the fatty acid, instead of the neutral fat, and combining
it directly with caustic alkali or carbonate, which is incorrectly
termed _carbonate saponification_, since it is merely neutralizing the
free fatty acid and thus is not a saponification in the true sense of
the word. No glycerine is directly obtained by this method, as it is
usually previously removed in the clearage of the fat by either the
Twitchell or autoclave saponification method.
In the methods thus outlined the one most generally employed is the full
boiled process to form a sodium soap. This method of making soap
requires close attention and a knowledge which can only be obtained by
constant practice. The stock, strength of lyes, heat, amount of salt or
brine added, time of settling, etc., are all influencing factors.
The principles involved in this process are briefly these:
The fat is partly saponified with weak lyes (usually those obtained from
a previous boiling in the strengthening change are used), and salt is
added to grain the soap. The mass is then allowed to settle into two
layers. The upper layer is partly saponified fat; the lower layer, or
spent lye, is a solution of salt, glycerine, and contains any albuminous
matter or any other impurity contained in the fat. This is known as the
_killing_ or glycerine change. Strong lyes are now added and the fat
entirely saponified, which is termed the _strengthening change_. The
mass is then allowed to settle and the fluid soap run off above the
"nigre." This operation is called the finish or _finishing_ change.
The method may be more fully illustrated by a concrete example of the
method of manufacture of a tallow base:
Charge--
Tallow 88 per cent.
Cocoanut oil 10 per cent.
Rosin w. w. 2 per cent.
Amount charge 10 tons
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