Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
4. The glycerine liquors are purer and thus the treatment of the lyes is
cheaper and simpler and the evaporation less difficult.
5. The glycerine can readily be evaporated to 90 per cent. crude rather
than 80 per cent. crude, thus saving drums, labor in handling and
freight. The glycerine furthermore receives a higher rating and price,
being known as saponification crude which develops no glycols in
refining it.
6. The fatty acids obtained by the Twitchell saponifier may be converted
into soap by carbonates, thus saving cost in alkali.
7. There is a decrease in the odor of many strong smelling stocks.
8. The glycerine may be obtained from half boiled and cold made soaps as
well as soft (potash) soaps.
While the advantages thus outlined are of decided value in the
employment of the Twitchell process, the one great disadvantage is that
the fatty acids obtained are rather dark in color and are not
satisfactorily employed for the making of a soap where whiteness of
color is desired.
To carry out the process the previously heated oil or fat to be
saponified is run into a lead lined tank. As greases and tallow often
contain impurities a preliminary treatment with sulfuric acid is
necessary. For a grease 1.25 per cent. of half water and half 66deg. B.
sulfuric acid is the approximate amount. The undiluted 66deg. B. acid
should never be added directly, as the grease would be charred by this.
The grease should be agitated by steam after the required percentage of
acid, calculated on the weight of the grease, has been added. The wash
lye coming off should be 7deg.-10deg. B. on a good clean grease or
15deg.-22deg. B. on cotton oil or a poor grease. As has been stated the
grease is heated before the acid is added or the condensation of the
steam necessitates the addition of more acid. After having boiled for
1-2 hours the grease is allowed to settle for 12 hours and run off
through a swivel pipe.
After the grease has been washed, as just explained, and settled, it is
pumped into a covered wooden tank containing an open brass coil. Some of
the second lye from a previous run is usually left in this tank and the
grease pumped into this. The amount of this lye should be about
one-third to one-half the weight of the grease so that there is about 60
per cent. by weight of grease in the tank after 24 hours boiling. Where
occasions arise when there is no second lye about 50 per cent. by weight
of distilled water to the amount of grease is run into the tank to
replace the lye. The saponifier is then added through a glass or granite
ware funnel after the contents of the tank have been brought to a boil.
If the boiling is to be continued 48 hours, 1 per cent. of saponifier is
added. For 24 hours boiling add 1.5 per cent. The boiling is continued
for 24-48 hours allowing 18 inches for boiling room or the grease will
boil over.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account