Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
As to the amount of saponifier to use on various stocks, this is best
determined by experiment as to how high a percentage gives dark colored
fatty acids. For good stock such as clean tallow, prime cottonseed oil,
corn oil, cocoanut oil and stock of this kind 0.75 per cent. saponifier
is sufficient. For poorer grades of tallow, house grease, poor
cottonseed oil, etc., 1 per cent. saponifier is required and for poorer
grade greases higher percentages. The percentage of fatty acids
developed varies in various stocks, and also varies with the care that
the operation is carried out, but is usually between 85 per cent.-95 per
cent. Due to the water taken up in the saponification process there is a
yield of about 103 pounds of fatty acids and glycerine for 100 pounds of
fat.
The Twitchell reagent has undoubtedly caused a decided advance in the
saponification of fats and oils and has been of great value to the soap
manufacturer, because with a small expenditure it is possible to compete
with the much more expensive equipment necessary for autoclave
saponification. The drawback, however, has been that the reagent
imparted a dark color to the fatty acids obtained, due to decomposition
products forming when the reagent is made, and hence is not suitable for
use in soaps where whiteness of color is desired.
There have recently been two new reagents introduced which act as
catalyzers in splitting fats, just as the Twitchell reagent acts, but
the fatty acids produced by the cleavage are of good color. The
saponification, furthermore, takes place more rapidly. These are the
Pfeilring reagent and Kontact reagent.
The Pfeilring reagent is very similar to the Twitchell reagent, being
made from hydrogenated castor oil and naphthalene by sulfonation with
concentrated sulfuric acid. It is manufactured in Germany and is being
extensively used in that country with good success.
The Kontact or Petroff reagent, discovered by Petroff in Russia, is made
from sulfonated mineral oils. Until very recently it has only been
manufactured in Europe, but now that it has been found possible to
obtain the proper mineral constituent from American petroleum, it is
being manufactured in this country, and it is very probable that it will
replace the Twitchell reagent because of the advantages derived by using
it, as compared to the old Twitchell reagent.
The method and equipment necessary for employing either the Pfeilring or
Kontact reagents is exactly the same as in using the Twitchell process.
AUTOCLAVE SAPONIFICATION.
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