Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The oils are first heated and run into this tank. The right temperature
to heat these to is about 1 degree to 2 degrees above their
solidification point. For liquid oils 23 degrees C. is the proper heat
as under 20 degrees C. the cleavage takes place slowly. Fats titering 44
degrees C. or above must be brought down in titer by mixing with them
oils of a lower titer as the ferment or enzyme is killed at about 45
degrees C. and thus loses its power of splitting. It is also necessary
to have the fat in the liquid state or the ferment does not act. The
proper temperature must be maintained with dry steam.
It is, of course, necessary to add water, which may be any kind desired,
condensed, water from steam coils, well, city, etc. From 30 per cent. to
40 per cent., on the average 35 per cent. of water is added, as the
amount necessary is regulated so as to not dilute the glycerine water
unnecessarily. To increase the hydrolysis a catalyzer, some neutral
salt, usually manganese sulfate is added in the proportion of 0.15 per
cent. appears to vary directly as the saponification number of the fat
or oil. The approximate percentages of fermentive substance to be added
to various oils and fats follow:
Cocoanut oil 8 %
Palm Kernel oil 8 %
Cottonseed oil 6-7 %
Linseed oil 4-5 %
Tallow oil 8-10%
The oil, water, manganese sulfate and ferment having been placed in the
tank in the order named, the mixture is agitated with air for about a
quarter of an hour to form an even emulsion, in which state the mass is
kept by stirring occasionally with air while the saponification is
taking place. A temperature is maintained a degree or two above the
titer point of the fat with closed steam which may be aided by covering
the tank for a period of 24 to 48 hours. The splitting takes place
rapidly at first, then proceeds more slowly. In 24 hours 80 per cent. of
the fats are split and in 48 hours 85 per cent. to 90 per cent.
When the cleavage has reached the desired point the mass is heated to 80
degrees-85 degrees C. with live or indirect steam while stirring with
air. Then 0.1 per cent.-0.15 per cent of concentrated sulfuric acid
diluted with water is added to break the emulsion. When the emulsion is
broken the glycerine water is allowed to settle out and drawn off. The
glycerine water contains 12 per cent. to 25 per cent. glycerine and
contains manganese sulfate, sulfuric acid and albuminous matter. Through
neutralization with lime at boiling temperature and filtration the
impurities can almost all be removed after which the glycerine water may
be fed to the evaporator. Should it be desired to overcome the trouble
due to the gypsum formed in the glycerine, the lime treatment may be
combined with a previous treatment of the glycerine water with barium
hydrate to remove the sulfuric acid, then later oxalic acid to
precipitate the lime.
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