Having grasped this, even partially, I will ask you to accompany me to
a remote corner of the domain of physics, with the view, however, of
showing that remoteness does not imply discontinuity. Let a certain
quantity of air at a temperature of 0°, contained in a perfectly
inexpansible vessel, have its temperature raised 1°. Let the same
quantity of air, placed in a vessel which permits the air to expand
when it is heated—the pressure on the air being kept constant during
its expansion—also have its temperature raised 1°. The quantities
of heat employed in the two cases are different. The one quantity
expresses what is called the specific heat of air at constant volume;
the other the specific heat of air at constant pressure.[21] It is an
instance of the manner in which apparently unrelated natural phenomena
are bound together, that from the calculated and observed velocities
of sound in air we can deduce the ratio of these two specific heats.
Squaring Newton’s theoretic velocity and the observed velocity, and
dividing the greater square by the less, we obtain the ratio referred
to. Calling the specific heat at constant volume C^{v}, and that
at constant pressure C^{p}; calling, moreover, Newton’s calculated
velocity V, and the observed velocity V′, Laplace proved that—
C^{p} V′^{2}
————— = —————
C^{v} V^{2}
Inserting the values of V and V′ in this equation, and making the
calculation, we find—
C^{p}
————— = 1·42.
C^{v}
Thus, without knowing either the specific heat at constant volume or
at constant pressure, Laplace found the ratio of the greater of them
to the less to be 1·42. It is evident from the foregoing formulæ that
the calculated velocity of sound, multiplied by the square root of this
ratio, gives the observed velocity.
But there is one assumption connected with the determination of this
ratio, which must be here brought clearly forth. It is assumed that
the heat developed by compression _remains in the condensed portion of
the wave_, and applies itself there to augment the elasticity; that no
portion of it is lost by radiation. If air were a powerful radiator,
this assumption could not stand. The heat developed in the condensation
could not then remain in the condensation. It would radiate all
round, lodging itself for the most part in the chilled and rarefied
portion of the wave, which would be gifted with a proportionate power
of absorption. Hence the direct tendency of radiation would be to
equalize the temperatures of the different parts of the wave, and
thus to abolish the increase of velocity which called forth Laplace’s
correction.[22]
§ 11. _Mechanical Equivalent of Heat deduced from Velocity of Sound_
Public-domain text, read in full here on John Shaqi.
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