The question, then, of the correctness of this ratio involves the other
and apparently incongruous question, whether atmospheric air possesses
any sensible radiative power. If the ratio be correct, the practical
absence of radiative power on the part of air is demonstrated. How then
are we to ascertain whether the ratio is correct or not? By a process
of reasoning which illustrates still further how natural agencies are
intertwined. It was this ratio, looked at by a man of genius, named
Mayer, which helped him to a clearer and a grander conception of the
relation and interaction of the forces of inorganic and organic nature
than any philosopher up to his time had attained. Mayer was the first
to see that the excess 0·42 of the specific heat at constant pressure
over that at constant volume was the quantity of heat consumed in the
work performed by the expanding gas. Assuming the air to be confined
laterally and to expand in a vertical direction, in which direction it
would simply have to lift the weight of the atmosphere, he attempted
to calculate the precise amount of heat consumed in the raising of
this or any other weight. He thus sought to determine the “mechanical
equivalent” of heat. In the combination of his data his mind was clear,
but for the numerical correctness of these data he was obliged to rely
upon the experimenters of his age. Their results, though approximately
correct, were not so correct as the transcendent experimental ability
of Regnault, aided by the last refinements of constructive skill,
afterward made them. Without changing in the slightest degree the
method of his thought or the structure of his calculation, the simple
introduction of the exact numerical data into the formula of Mayer
brings out the true mechanical equivalent of heat.
But how are we able to speak thus confidently of the accuracy of this
equivalent? We are enabled to do so by the labors of an Englishman, who
worked at this subject contemporaneously with Mayer; and who, while
animated by the creative genius of his celebrated German brother,
enjoyed also the opportunity of bringing the inspirations of that
genius to the test of experiment. By the immortal experiments of Mr.
Joule, the mutual convertibility of mechanical work and heat was first
conclusively established. And “Joule’s equivalent,” as it is rightly
called, considering the amount of resolute labor and skill expended
in its determination, is almost identical with that derived from the
formula of Mayer.
§ 12. _Absence of Radiative Power of Air deduced from Velocity of Sound_
Public-domain text, read in full here on John Shaqi.
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