These are instances of selective radiation. We will now turn to
absorption. If we first get a continuous spectrum from our lantern and
then interpose substances in the path of the beam, we can examine their
effects on the light. If we first use a piece of neutral-tinted glass,
which is a representative of a great many substances which do, for
stopping light, what solids and liquids do for giving light—namely, it
cuts off a portion of every colour; the spectrum on the screen will be
dimmed; here we have a case of general absorption. If, instead of this,
we hold in the beam a vessel containing magenta, a dark band in the
spectrum is seen, and if we put a test-tube in its place containing
iodine vapour, a number of well-defined lines pervading the spectrum is
observed. In these cases clearly, the magenta in one case, and the
iodine vapour in the other, have cut off certain colours, and so the
slit is not painted in these colours, and dark lines or bands appear.
These are instances of _selective absorption_, certain rays are selected
and absorbed, while others pass on unheeded. The easiest method of
performing these absorption experiments in the case of liquids is to
place the substance in a test-tube in front of the slit of the
spectroscope, as shown in Fig. 183, and point the collimator to a strong
light.
Besides the absorption by liquids, the vapours of the metals also absorb
selectively, and if a tube containing a piece of sodium and filled with
hydrogen (so that the metal will not get oxidized) is placed in the path
of the rays, and the sodium heated, the spectrum is at first unaffected,
but as the sodium gets hot and its vapour comes off, we can mark its
effect on the spectrum. We see a dark line beginning to appear in the
yellow, finally the whole light of that particular colour is absorbed,
and we have a dark line in its place. To sum up then:—
We get from solids, when heated, general radiation, and when they act as
absorbers, we get general absorption; from gases and vapours we get
selective radiation and selective absorption.
[Illustration:
FIG. 183.—Spectroscope arranged for showing Absorption.
]
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