How does an atom float on a sunbeam? The possibility depends on the
pressure of light to which we have already referred (p. 26). The
sunlight travelling outwards carries a certain outward momentum; if the
atom absorbs the light it absorbs also the momentum and so receives a
tiny impulse outwards. This impulse enables it to recover the ground it
was losing in falling towards the sun. The atoms in the chromosphere
are kept floating above the sun like tiny shuttlecocks, dropping a
little and then ascending again from the impulse of the light. Only
those atoms which can absorb large quantities of sunlight in proportion
to their weight will be able to float successfully. We must look rather
closely into the mechanism of absorption of the calcium atom if we are
to see why it excels the other elements.
The ordinary calcium atom has two rather loose electrons in its
attendant system; the chemists express this by saying that it is a
divalent element, the two loose electrons being especially important in
determining the chemical behaviour. Each of these electrons possesses
a mechanism for absorbing light. But under the conditions prevailing
in the chromosphere one of the electrons is broken away, and the
calcium atoms are in the same smashed state that gives rise to the
‘fixed lines’ in the interstellar cloud. The chromospheric calcium
thus supports itself on what sunlight it can gather in with the one
loose electron remaining. To part with this would be fatal; the atom
would no longer be able to absorb sunlight, and would drop like a
stone. It is true that after two electrons are lost there are still
eighteen remaining; but these are held so tightly that sunlight has no
effect on them and they can only absorb shorter waves which the sun
does not radiate in any quantity. The atom therefore could only save
itself if it restored its main absorbing mechanism by picking up a
passing electron; it has little chance of catching one in the rarefied
chromosphere, so it would probably fall all the way to the sun’s
surface.
There are two ways in which light can be absorbed. In one the atom
absorbs so greedily that it bursts, and the electron scurries off with
the surplus energy. That is the process of ionization which was shown
in Fig. 5. Clearly this cannot be the process of absorption in the
chromosphere because, as we have seen, the atom cannot afford to lose
the electron. In the other method of absorption the atom is not quite
so greedy. It does not burst, but it swells visibly. To accommodate the
extra energy the electron is tossed up into a higher orbit. This method
is called excitation (cf. p. 59). After remaining in the excited orbit
for a little while the electron comes down again spontaneously. The
process has to be repeated 20,000 times a second in order to keep the
atom balanced in the chromosphere.
Public-domain text, read in full here on John Shaqi.
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