The point we are leading up to is, Why should calcium be able to float
better than other elements? It has always seemed odd that a rather
heavy element (No. 20 in order of atomic weight) should be found in
these uppermost regions where one would expect only the lightest atoms.
We see now that the special skill demanded is to be able to toss up an
electron 20,000 times a second without ever making the fatal blunder
of dropping it. That is not easy even for an atom. Calcium[23] scores
because it possesses a possible orbit of excitation only a little way
above the normal orbit so that it can juggle the electron between
these two orbits without serious risk. With most other elements the
first available orbit is relatively much higher; the energy required
to reach this orbit is not so very much less than the energy required
to detach the electron altogether; so that we cannot very well have a
continuous source of light capable of causing the orbit-jumps without
sometimes overdoing it and causing loss of the electron. It is the
wide difference between the energy of excitation and the energy of
ionization of calcium which is so favourable; the sun is very rich in
ether-waves capable of causing the first, and is almost lacking in
ether-waves capable of causing the second.
The average time occupied by each performance is ¹⁄₂₀₀₀₀th of a second.
This is divided into two periods. There is a period during which the
atom is patiently waiting for a light-wave to run into it and throw
up the electron. There is another period during which the electron
revolves steadily in the higher orbit before deciding to come down
again. Professor Milne has shown how to calculate from observations of
the chromosphere the durations of both these periods. The first period
of waiting depends on the strength of the sun’s radiation. But we focus
attention especially on the second period, which is more interesting
because it is a definite property of the calcium atom, having nothing
to do with local circumstances. Although we measure it for ions in
the sun’s chromosphere, the same result must apply to calcium ions
anywhere. Milne’s result is that an electron tossed into the higher
orbit remains there for an average time of a hundred-millionth of a
second before it spontaneously drops back again. I may add that during
this brief time it makes something like a million revolutions in the
upper orbit.
Public-domain text, read in full here on John Shaqi.
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