Perhaps this is a piece of information that you were not particularly
burning to know. I do not think it can be called interesting except to
those who make a hobby of atoms. But it does seem to me interesting
that we should have to turn a telescope and spectroscope on the sun to
find out this homely property of a substance which we handle daily. It
is a kind of measurement of immense importance in physics. The theory
of these atomic jumps comes under the quantum theory which is still
the greatest puzzle of physical science; and it is greatly in need of
guidance from observation on just such a matter as this. We can imagine
what a sensation would be caused if, after a million revolutions round
the sun, a planet made a jump of this kind. How eagerly we should try
to determine the average interval at which such jumps occurred! The
atom is rather like a solar system, and it is not the less interesting
because it is on a smaller scale.
There is no prospect at present of measuring the time of relaxation
of the excited calcium atom in a different way. It has, however, been
found possible to determine the corresponding time for one or two other
kinds of atoms by laboratory experiments. It is not necessary that
the time should be at all closely the same for different elements;
but laboratory measurements for hydrogen also give the period as a
hundred-millionth of a second, so there is no fault to find with the
astronomical determination for calcium.
The excitation of the calcium atom is performed by light of two
particular wave-lengths, and the atoms in the chromosphere support
themselves by robbing sunlight of these two constituents. It is true
that after a hundred-millionth of a second a relapse comes and the
atom has to disgorge what it has appropriated; but in re-emitting
the light it is as likely to send it inwards as outwards, so that
the _outflowing_ sunlight suffers more loss than it recovers.
Consequently, when we view the sun through this mantle of calcium the
spectrum shows gaps or dark lines at the two wave-lengths concerned.
These lines are denoted by the letters H and K. They are not entirely
black, and it is important to measure the residual light at the centre
of the lines, because we know that it must have an intensity just
strong enough to keep calcium atoms floating under solar gravity; as
soon as the outflowing light is so weakened that it can support no
more atoms it can suffer no further depredations, and so it emerges
into outer space with this limiting intensity. The measurement gives
numerical data for working out the constants of the calcium atom
including the time of relaxation mentioned above.
Public-domain text, read in full here on John Shaqi.
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