Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
_Raw materials._—Although the chief raw materials consumed in the
synthetic resin industry are coal-tar derivatives and formaldehyde, many
others are utilized. The rapid expansion of the industry has created new
demands for materials in increasing quantities and has not only increased
the markets for well-known materials but has resulted in the production
on a huge scale of materials entirely new to commerce. Practically all
the raw materials now used can be derived from a few natural substances,
such as air, water, coal, petroleum crudes, salt, sulphur, and limestone.
The air yields nitrogen which may be converted to ammonia, a raw
material for urea, one of the components of the urea resins. Coal, as
is well known, yields a great variety of substances, many of which are
essential to synthetic resin manufacture. Benzene is the starting point
for synthetic phenol; naphthalene is used to make phthalic anhydride
and maleic anhydride; coke is converted to calcium carbide, which in
turn yields acetylene, acetic acid, and many other synthetics; carbon
monoxide which is converted to methanol and formaldehyde; and the natural
tar acids such as phenol, the cresols, and the xylenols. Limestone is a
component of calcium carbide, and salt yields needed alkalies and acids.
Water is broken down, and the hydrogen is converted to ammonia, methanol,
formaldehyde, and ethylene.
Some idea of the expansion in production of these raw materials whose
principal use is in synthetic resins may be had by comparing the output
in 1923 of tar acids, formaldehyde, phthalic anhydride, maleic anhydride,
urea, vinyl acetate, and vinyl chloride, which amounted to 35 million
pounds, with the output of 270 million pounds in 1936. The manufacture of
these materials is largely by coal-tar distilling companies and makers of
chemicals.
_Resins._—The coal-tar resins are the most important in quantity, value,
and variety of application. This class includes four groups: (_a_) tar
acid, (_b_) alkyd, (_c_) coumarone and indene, and (_d_) polystyrene. Of
these, resins from tar acids (phenol, cresols, and xylenols) are produced
in the largest quantity, the output having increased from about 15
million pounds in 1932 to about 80 million pounds in 1937. In the latter
year about 40 percent of the consumption of tar acid resins was in molded
articles, 25 percent in paint and varnishes, 20 percent in laminated
products, and 15 percent in miscellaneous uses.
The alkyd resins have shown a remarkable increase in output. Production
totaled slightly less than 10 million pounds in 1933; in 1937 it amounted
to about 61 million pounds. Practically all of the alkyds have been
consumed in paints and varnishes.
The coumarone and indene resins have increased steadily over a number of
years and are now one of the most important groups.
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