Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
The early work done on phenol-formaldehyde resins gave dark-colored
products which were too hard and brittle to be machined or worked on
a lathe. Investigations by F. Pollak and A. Ostersetzer, in Vienna,
resulted in a process for the manufacture of cast phenolic resin with
a range of color possibilities from water-white transparency through
all shades and degrees of translucency and opaqueness. This product is
cast into sheets, rods, tubes, and special castings, all of which may
be turned or milled on automatic machines. United States Patent No.
1,854,600, issued April 19, 1932, to F. Pollak and A. Ostersetzer and
assigned to Pollopas, Ltd., London, is considered the basic patent for
cast phenolic resins. American rights under this and related patents
are owned by the Catalin Corporation of America who have licensed other
domestic makers. The German equivalent of rights under this patent is
owned by a subsidiary of I. G. Farbenindustrie Aktiengesellschaft and
rights under the French equivalent by Établissements Kuhlmann.
In the early days of the phenol-formaldehyde resin industry (1909-16)
there was considerable uneasiness about the supply of phenol. World
production was not large and Germany and England controlled most of
it. The output of the United States was almost entirely for medicinal
use, although our potential production was large (see p. 111). This
situation caused many research workers to study the resins made from
other tar acids, principally meta and para cresols and the xylenols. The
investigations resulted in many new types of resins and in modifications
of the phenol-formaldehyde type. The World War changed conditions
materially. Imports of phenol were shut off and prices soared. Production
of synthetic phenol was begun, and, although the wartime production
went into explosives, its development had an important bearing on the
synthetic resin industry. Unusual demand for phenol, toluene, and other
coal-tar crudes resulted in a great expansion of production. With the
cessation of hostilities there was an ample supply of cheap phenol and
the expansion of the coal-tar industry continued so that the supply of
tar acids kept pace with the new demand for use in the production of
synthetic resin.
In 1926, the early patents on resins from tar acids began to expire
and the second era of the industry began. Since that year most of
the research work has been for materials that would give different
properties to the resultant resins. The past 10 years have seen a
greater diversification in the manufacture of resins from tar acids and
substantial reductions in their prices. Tar-acid resins averaged $1.29
per pound in 1920, 23 cents per pound in 1934, and 19 cents per pound in
1937. The production of certain resins of this class which are soluble in
drying oils has been an important achievement. They yield varnishes of
improved type that are quick-drying.
The three stages of a tar-acid resin.
Public-domain text, read in full here on John Shaqi.
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