Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Fahrion has shown that, during the tanning process, the quinone loses
its active oxygen, and this can only be brought about by the amino group
of the hide protein, the amino group only being capable of effecting
reduction of the quinone. An analogy is here offered by
dianilinoquinone. A spent quinone liquor contains considerable amounts
of hydroquinone. The tannage may also be effected by exposing pelt
saturated with hydroquinone to oxidation by the air. The pelt, which is
unaltered by the hydroquinone bath, on being removed from the latter,
and in the presence of alkali, assumes a red colour at first, which
changes into violet, blue, and finally brown, the pelt being thereby
converted into a quinone-tanned leather.
It may be noted that quinone only effects pseudo-tannage; quinone mixed
with water deposits, in time, a black amorphous substance practically
insoluble in water. This substance is easily adsorbed by hide powder,
but is not capable of converting the latter into that insoluble form
into which it is converted by the natural tannins.
Amongst polyhydric alcohols, the behaviour of the methyl ester of
catechol, _guaiacol_ was investigated. The sulphonic acid was prepared
by heating guaiacol with concentrated sulphuric acid, the resulting
water-soluble product possessing a light, brownish-green colour. On
condensing the sulphonic acid with formaldehyde, the same precautions
were observed as in the case of resorcinol, but complete fixation of the
formaldehyde could only be obtained by finally heating the product for a
short time over a free flame, at about 105° C. Condensation was
indicated by the brownish appearance of the liquid. No insoluble
products were formed. The condensation product easily dissolves in
water, the solution assuming a rich brown colour and exhibiting the
following reactions: gelatine is completely precipitated, aniline
hydrochloride produces opalescence, and ferric chloride a deep brown
coloration.
Tannage, with the partly neutralised product, was rapid, the pelt being
nearly tanned through in twenty-four hours, excepting a small white
streak in the middle; after a further twenty-four hours this streak had
vanished, and the completely tanned, dark grey-coloured leather, after
washing, fat-liquoring, and drying, was soft, full, and of good tensile
strength, very similar to the leather yielded by the
catechol-condensation product.
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