Synthetic Tannins, Their Synthesis, Industrial Production and Application — John Shaqi
Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Of the nitro-compounds, trinitrophenol, C_6H_2(NO_2)_3OH (picric acid),
was investigated. If a concentrated solution of picric acid is brought
into contact with pelt it will penetrate the latter completely in a few
days; it is, however, difficult to fat-liquor the resultant leather,
since the fat is absorbed only with difficulty. If a pelt treated in
this way be dried, a soft but rather flat leather results, the colour of
which easily rubs off, the leather also tasting intensely bitter. These
disagreeable qualities prevent a general use of this material for
tanning purposes; in spite of them, however, picric acid, in admixture
with boracic acid, salicylic acid, and glycerol, is used in the
production of the so-called transparent leather. The latter is very
flexible and possesses great tensile strength, but loses the latter
quality when exposed to heat, and, when stored, also loses its
flexibility. By simply washing with water, the leather is reconverted
into pelt.
When picric acid is treated with hot sulphuric acid and formaldehyde
gradually added, a dark coloured water-soluble condensation product is
formed which strongly precipitates gelatine. Exposed to the action of
bromine, the condensation product yields a mass which is insoluble in
water.
Experience has taught that the amino bodies--the basic N-derivatives of
the phenols--do not yield substances possessing tannoid properties on
condensation. On account of their importance, however, a few have been
included in this series of investigations.
Aminobenzene, C_6H_5NH_2, aniline, treated with sulphuric acid, yields
the water-soluble aniline sulphate, which, on cautious addition of
formaldehyde, yields a reddish-coloured gel, insoluble in water, in
addition to a small volume of a reddish-yellow liquid. The latter
precipitates gelatine, but is not capable of converting pelt into
leather. The insoluble gel is likewise insoluble in alcohol, so that
tanning experiments with this substance are excluded.
Dimethylaniline, C_6H_5N(CH_3)_2, when treated with sulphuric acid, yields a
product soluble in water which neither reacts with nor fixes
formaldehyde. Hence the substance does not precipitate gelatine.
If, on the other hand, nitrosodimethylaniline,
NO
|
C_6H_4
|
(CH_3)_2
is sulphonated, and the water-soluble sulphonation product heated with
formaldehyde for some time, the product remains soluble in water and
precipitates gelatine. No tanning effect could, however, be detected.
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