The fact of the periodic relations among the elements, and of
progressive properties such as those shown in X-ray spectra (which
we shall consider later on), is enough to make it highly probable
[Pg 21]
that there are relations between different kinds of atoms, of a sort
which implies that they are all built out of common materials, which
must be regarded as the true “atoms” in the philosophical sense,
i.e. the indivisible constituents of all matter. Chemical atoms are
not indivisible, but are composed of simpler constituents which
are indivisible, so far as our present knowledge goes. Without the
knowledge of the periodic law, it is probable that the modern theories
of the constitution of atoms would never have been discovered; per
contra, the facts embodied in the periodic law form an essential
part of the basis for these theories. The broad lines of atomic
constitution will be explained in the next chapter.
[2]
The Theory of Spectra and Atomic Constitution,
Cambridge, 1922, pp. 112-3.
[Pg 22]
III.
ELECTRONS AND NUCLEI
AN atom, as we saw in Chapter I, consists, like the solar system, of
a number of planets moving round a central body, the planets being
called “electrons” and the central body a “nucleus.” But the planets
are not attached as firmly to the central body as they are in the solar
system. Sometimes, under outside influences, a planet flies off, and
either becomes attached to some other system, or wanders about for a
while as a free electron. Under certain circumstances, the path of a
free electron can actually be photographed; so can the paths of helium
nuclei that are momentarily destitute of attendant electrons. This is
done by making them travel through water vapour, which enables each
to collect a little cloud, and so become large enough to be visible
with a powerful microscope. These observations of individual electrons
and helium nuclei are extraordinarily instructive. They travel most
of their journey in nearly straight lines, but are liable to sudden
[Pg 23]
deviations when they find themselves very near to the electrons or
nuclei of atoms that stand in their way. Helium nuclei are much less
easily deflected from the straight line than electrons, showing that
they have much greater mass. By exposing these particles to electric
and magnetic forces and observing the effect upon their motion, it is
possible to calculate their velocity and their mass. By one means or
another, it is possible to find out just as much about them as we can
find out about larger bodies.
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