As we pass up the periodic series of the elements, the positive
charge of electricity in the nucleus increases by one unit with each
step. Helium, the second element in the table, has exactly twice as
much positive electricity in its nucleus as there is in the nucleus
of hydrogen; lithium, the third element, has three times as much;
oxygen, the eighth, has eight times as much; uranium, the ninety-second
(counting the gaps), has ninety-two times as much. Corresponding to
this increase in the positive electricity of the nucleus, the atom in
[Pg 30]
its unelectrified state has more electrons revolving round the nucleus.
Helium has two electrons, lithium three, and so on, until we come to
uranium, like the Grand Turk, with ninety-two consorts revolving round
him. In this way the negative electricity of the electrons exactly
balances the positive electricity of the nucleus, and the atom as a
whole is electrically neutral. When, by any means, an atom is robbed
of one of its electrons, it becomes positively electrified; if it is
robbed of two electrons, it becomes doubly electrified and remains
electrified until it has an opportunity of annexing from elsewhere as
many electrons as it has lost. A body can be negatively electrified by
containing free electrons; an atom may for a short time have more than
its proper number of electrons, and thus become negatively electrified,
but this is an unstable condition, except in chemical combinations.
Nobody knows exactly how the electrons are arranged in other atoms
than hydrogen. Even with helium, which has only two electrons, the
mathematical problems are too difficult to be solved completely; and
when we come to atoms that have a multitude of electrons, we are
reduced largely to guesswork. But there is reason to think that the
electrons are arranged more or less in rings, the inner rings being
[Pg 31]
nearer to the nucleus than the outer ones. We know that the electrons
must all revolve about the nucleus in orbits which are roughly circles
or ellipses, but they will be perturbed from the circular or elliptic
path by the repulsions of the other electrons. In the solar system,
the attractions which the planets exercise upon each other are very
minute compared to the attraction of the sun, so that each planet moves
very nearly as if there were no other planets. But the electrical
forces between two electrons are not very much less strong than the
forces between electrons and nucleus at the same distance. In the case
of helium, they are half as strong; with lithium, a third as strong,
and so on. This makes the perturbations much greater than they are in
the solar system, and the mathematics correspondingly more difficult.
Moreover we cannot actually observe the orbits of the electrons, as we
can those of the planets; we can only infer them by calculations based
upon data derived mainly from the spectrum of the element concerned,
including the X-ray spectrum.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account