We shall have more to say at a later stage about the nature of these
rings, which cannot be as simple as was supposed at first. The
first hypothesis was that the electrons were like the people in a
[Pg 32]
merry-go-round, all going round in circles, some in a small circle near
the centre, others in a larger circle, others in a still larger one.
But for various reasons the arrangement cannot be as simple as that.
In spite of uncertainties of detail, however, it remains practically
certain that there are successive rings of electrons: one ring in
atoms belonging to the first period, two in the second period, three
in the third, and so on. Each period begins with an alkali, which has
only one electron in the outermost ring, and ends with an inert gas,
which has as many electrons in the outermost ring as it can hold. It
is impossible to get a ring to hold more than a certain number of
electrons, though it has been suggested by Niels Bohr, in an extremely
ingenious speculation, that a ring can hold more electrons when it
has other rings outside it than when it is the outer ring. His theory
accounts extraordinarily well for the peculiarities of the periodic
table, and is therefore worth understanding, though it cannot yet be
regarded as certainly true.
The previous view was that each ring, when complete, held as many
electrons as there are elements in the corresponding period. Thus
the first period contains only two elements (hydrogen and helium);
therefore the innermost ring, which is completed in the helium atom,
[Pg 33]
must contain two electrons. This remains true on Bohr’s theory. The
second period consists of eight elements, and is completed when we
reach neon. The unelectrified atom of neon therefore, will have two
electrons in the inner ring and eight in the outer. The third period
again consists of eight elements, ending with argon; therefore argon,
in its neutral state, will have a third ring consisting of a further
eight electrons. So far, we have not reached the parts of the periodic
table in which there are irregularities, and therefore Bohr accepts
the current view, except for certain refinements which need not
concern us at present. But in the fourth period, which consists of
18 elements, there are a number of elements which do not correspond
to earlier ones in their chemical and spectroscopic properties. Bohr
accounts for this by supposing that the new electrons are not all in
the new outermost ring, but are some of them in the third ring, which
is able to hold more when it has other electrons outside it. Thus
krypton, the inert gas which completes the fourth period, will still
have only eight electrons in its outer ring, but will have eighteen in
the third ring. Some elements in the fourth period differ from their
immediate predecessors, not as regards the outer ring, but by having
[Pg 34]
one more electron in the third ring. These are the elements that do not
correspond accurately to any elements in the third period. Similarly
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