the fifth period, which again consists of 18 elements, will add its new
electrons partly in the new fifth ring, partly in the fourth, ending
with xenon, which will have eight electrons in the fifth ring, eighteen
in the fourth, and the other rings as in krypton. In the sixth period,
which has 32 elements, the new electrons are added partly in the sixth
ring, partly in the fifth, and partly in the fourth; the rare earths
are the elements which add new electrons in the fourth ring. Niton,
the inert gas which ends the sixth period, will, according to Bohr’s
theory, have its first three rings the same as those of krypton and
xenon, but its fourth ring will have 32 electrons, its fifth 18, and
its sixth eight. This theory has very interesting niceties, which,
however, cannot be explained at our present stage.
The chemical properties of an element depend almost entirely upon the
outer ring of electrons, and that is why they are periodic. If we
accept Bohr’s theory, the outer ring, when it is completed, always has
eight electrons, except in hydrogen and helium. There is a tendency for
atoms to combine so as to make up the full number of electrons in the
[Pg 35]
outer ring. Thus an alkali, which has one electron in the outer ring,
will combine readily with an element that comes just before an inert
gas, and so has one less electron in the outer ring than it can hold.
An element which has two electrons in the outer ring will combine with
an element next but one before an inert gas, and so on. Two atoms of
an alkali will combine with one atom of an element next but one before
an inert gas. An inert gas, which has its outer ring already complete,
will not combine with anything.
[Pg 36]
IV.
THE HYDROGEN SPECTRUM
THE general lines of atomic structure which have been sketched
in previous chapters have resulted largely from the study of
radio-activity, together with the theory of X-rays and the facts
of chemistry. The general picture of the atom as a solar system of
electrons revolving about a nucleus of positive electricity is derived
from a mass of evidence, the interpretation of which is largely due
to Rutherford; to him also is due a great deal of our knowledge of
radio-activity and of the structure of nuclei. But the most surprising
and intimate secrets of the atom have been discovered by means of
the spectroscope. That is to say, the spectroscope has supplied the
experimental facts, but the interpretation of the facts required an
extraordinarily brilliant piece of theorizing by a young Dane, Niels
Bohr, who, when he first propounded his theory (1913), was still
working under Rutherford. The original theory has since been modified
and developed, notably by Sommerfeld, but everything that has been
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done since has been built upon the work of Bohr. This chapter and the
next will be concerned with his theory in its original and simplest
form.
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