Let us first consider the results to which Bohr was led, and afterwards
the reasoning by which he was led to them. We will assume, to begin
with, that the electron in a hydrogen atom, in its steady states, goes
round the nucleus in a circle, and that the different steady states
only differ as regards the size of the circle. As a matter of fact,
the electron moves sometimes in a circle and sometimes in an ellipse;
but Sommerfeld, who showed how to calculate the elliptical orbits that
may occur, also showed that, so far as the spectrum is concerned, the
result is very nearly the same as if the orbit were always circular. We
may therefore begin with the simplest case without any fear of being
misled by it. The circles that are possible on Bohr’s theory are also
possible on the more general theory, but certain ellipses have to be
added to them as further possibilities.
According to Newtonian dynamics, the electron ought to be capable of
revolving in any circle which had the nucleus in the centre, or in any
ellipse which had the nucleus in a focus; the question what orbit it
would choose would depend only upon the velocity and direction of its
[Pg 52]
motion at a given moment. Moreover, if outside influences increased
or diminished its energy, it ought to pass by continuous graduations
to a larger or smaller orbit, in which it would go on moving after
the outside influences were withdrawn. According to the theory of
electrodynamics, on the other hand, an atom left to itself ought
gradually to radiate its energy into the surrounding æther, with the
result that the electron would approach continually nearer and nearer
to the nucleus. Bohr’s theory differs from the traditional views on
all these points. He holds that, among all the circles that ought to
be possible on Newtonian principles, only a certain infinitesimal
selection are really possible. There is a smallest possible circle,
which has a radius of about half a hundredth millionth of a centimetre.
This is the commonest circle for the electron to choose. If it does
not move in this circle, it cannot move in a circle slightly larger,
but must hop at once to a circle with a radius four times as large.
If it wants to leave this circle for a larger one, it must hop to one
with a radius nine times as large as the original radius. In fact, the
only circles that are possible, in addition to the smallest circle, are
those that have radii 4, 9, 16, 25, 36 ... times as large. (This is
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the series of square numbers, the same series that came in finding a
formula for the hydrogen spectrum.) When we come to consider elliptical
orbits, we shall find that there is a similar selection of possible
ellipses from among all those that ought to be possible on Newtonian
principles.
Public-domain text, read in full here on John Shaqi.
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