The atom has least energy when the orbit is smallest; therefore the
electron cannot jump from a smaller to a larger orbit except under the
influence of outside forces. It may be attracted out of its course by
some passing positively electrified atom, or repelled out of its course
by a passing electron, or waved out of its course by light-waves. Such
occurrences as these, according to the theory, may make it jump from
one of the smaller possible circles to one of the larger ones. But
when it is moving in a larger circle it is not in such a stable state
as when it is in a smaller one, and it can jump back to a smaller
circle without outside influences. When it does this, it will emit
light, which will be one or other of the lines of the hydrogen spectrum
according to the particular jump that is made. When it jumps from the
circle of radius 4 to the smallest circle, it emits the line whose
wave-number is ¾ of Rydberg’s constant. The jump from radius 9 to the
smallest circle gives the line which is ⁸⁄₉ of Rydberg’s constant; the
[Pg 54]
jump from radius 9 to radius 4 gives the line which is ⁵⁄₃₆ (i.e. ¼ = ⅑)
of Rydberg’s constant, and so on. The reasons why this occurs will
be explained in the next chapter.
When an electron jumps from one orbit to another, this is supposed to
happen instantaneously, not merely in a very short time. It is supposed
that for a time it is moving in one orbit, and then instantaneously it
is moving in the other, without having passed over the intermediate
space. An electron is like a man who, when he is insulted, listens at
first apparently unmoved, and then suddenly hits out. The process by
which an electron passes from one orbit to another is at present quite
unintelligible, and to all appearance contrary to everything that has
hitherto been believed about the nature of physical occurrences.
Public-domain text, read in full here on John Shaqi.
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